{"id":"W2810253518","doi":"10.1002/anie.201806640","title":"A Stable Crown Ether Complex with a Noble‐Gas Compound","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":35,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Crown ether; Xenon; Chemistry; Noble gas; Denticity; Ether; Adduct; Crystallography; Ligand (biochemistry); Oxygen atom; 18-Crown-6; Crystal structure; Molecule; Ion; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001089733,0.0001972588,0.000154708,0.00005753735,0.000181044,0.0001198606,0.000294221,0.0001504742,0.01401546],"category_scores_gemma":[0.00002549424,0.0001659264,0.00006547356,0.0001180048,0.0002130328,0.0002339448,0.00006849894,0.0002424908,0.000232379],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000237229,"about_ca_system_score_gemma":0.0000670983,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001202126,"about_ca_topic_score_gemma":0.00003340999,"domain_scores_codex":[0.9987397,0.000007899733,0.0002338214,0.0003139692,0.0004403166,0.0002643439],"domain_scores_gemma":[0.999063,0.00006382226,0.0001371633,0.0002327798,0.0004214217,0.00008187158],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006649462,0.0001836517,0.0003066805,0.00002818528,0.0002680947,0.00003288199,0.0003950087,0.00001020483,0.9366028,0.0009283667,0.06033095,0.0002482722],"study_design_scores_gemma":[0.000977402,0.00007597927,0.0001308868,0.00009663919,0.00002831121,0.0001231101,0.0001295962,0.0003792882,0.790934,0.0008266761,0.206086,0.0002120441],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5429715,0.00007697757,0.003958242,0.003192135,0.001669068,0.0001136096,0.0001850309,0.0003520585,0.4474814],"genre_scores_gemma":[0.98849,0.00001585544,0.0008026228,0.0004229243,0.003179404,0.00002047908,0.0005069884,0.00003942701,0.006522307],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4455185,"threshold_uncertainty_score":0.9868858,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01630745096916371,"score_gpt":0.2435369541580802,"score_spread":0.2272295031889165,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}