{"id":"W2810724359","doi":"10.1039/c8cc04535f","title":"Transforming benzylideneamine N,C-chelate boron compounds to BN-cycloocta-/cyclohepta-trienes bearing a tetrasubstituted BN unit <i>via</i> photoisomerization","year":2018,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"China Scholarship Council; Natural Sciences and Engineering Research Council of Canada; Government of Canada","keywords":"Photoisomerization; Chemistry; Boron; Chelation; Bearing (navigation); Medicinal chemistry; Stereochemistry; Catalysis; Organic chemistry; Isomerization; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006982687,0.0002308225,0.0001005437,0.0001126174,0.0001120544,0.0001486238,0.000169584,0.0001360789,0.001815184],"category_scores_gemma":[0.00009414922,0.00009758522,0.00009652047,0.0001174743,0.0001041083,0.00018115,0.0001268629,0.0002285036,0.0003680235],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002248649,"about_ca_system_score_gemma":0.0001479133,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007351429,"about_ca_topic_score_gemma":0.002305798,"domain_scores_codex":[0.9999468,0.000005929923,0.000003381127,0.00001155808,0.00001155511,0.00002082966],"domain_scores_gemma":[0.9999515,0.000007609814,0.00001602602,0.000005220661,0.000008249425,0.00001143005],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000596033,0.00001333265,0.00005485836,0.00003233983,0.000002547471,0.00003034522,0.0000179891,0.00007424318,0.9978088,0.0001889963,0.00003602749,0.001681111],"study_design_scores_gemma":[0.000005957925,0.00009510397,0.0003090433,0.000002247926,0.000002839488,0.00004559658,0.000007831993,0.0001658023,0.998108,0.00001328279,0.001242303,0.000001988762],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9889616,0.0004631643,0.00276902,0.00003839525,0.00003107759,0.00003623214,0.0001830795,0.00006134713,0.007456101],"genre_scores_gemma":[0.9942161,0.0004551303,0.002001068,0.00003101335,0.000004082852,0.00002193872,0.0001677526,0.00002503809,0.003077957],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001815184,"threshold_uncertainty_score":0.006072342,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02541085021535906,"score_gpt":0.2736791719257544,"score_spread":0.2482683217103953,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}