{"id":"W2811197006","doi":"10.1016/j.chempr.2018.06.002","title":"Hole Catalysis as a General Mechanism for Efficient and Wavelength-Independent Z → E Azobenzene Isomerization","year":2018,"lang":"en","type":"article","venue":"Chem","topic":"Photochromic and Fluorescence Chemistry","field":"Materials Science","cited_by":101,"is_retracted":false,"has_abstract":false,"ca_institutions":"","funders":"Fonds Québécois de la Recherche sur la Nature et les Technologies; European Research Council; Alexander von Humboldt-Stiftung; Daimler und Benz Stiftung; Fonds de recherche du Québec – Nature et technologies; Deutsche Forschungsgemeinschaft","keywords":"Azobenzene; Isomerization; Photochemistry; Catalysis; Electrochemistry; Excited state; Methylene; Materials science; Chemistry; Combinatorial chemistry; Molecule; Physical chemistry; Organic chemistry; Electrode; Physics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003532126,0.0006229052,0.000350706,0.0004015773,0.0003531748,0.0008880126,0.0007930264,0.000627696,0.002457937],"category_scores_gemma":[0.0002911998,0.0002873887,0.0003477398,0.0002194548,0.0007531597,0.001141649,0.0009144015,0.001032114,0.0007272585],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005502297,"about_ca_system_score_gemma":0.0002990815,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003740221,"about_ca_topic_score_gemma":0.0004270088,"domain_scores_codex":[0.9998298,0.00001434386,0.00001154577,0.00004378308,0.00003336278,0.00006717559],"domain_scores_gemma":[0.9999418,0.00001805397,0.000007652569,0.00001551558,0.000006585375,0.00001039084],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001760373,0.000121914,0.0004829979,0.0002169986,0.00003424708,0.0005402447,0.000152641,0.001154308,0.8992358,0.07948958,0.001603007,0.01679231],"study_design_scores_gemma":[0.00004305401,0.0001704502,0.0002851321,0.000006951296,0.00001600445,0.0003224149,0.00003942713,0.004385501,0.9828667,0.006266234,0.005577614,0.00002048617],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8245577,0.002711756,0.1324185,0.001965948,0.0007230951,0.0004686999,0.0006740341,0.001728184,0.03475216],"genre_scores_gemma":[0.9898815,0.0007359615,0.006149781,0.0001228491,0.00002700415,0.0000547092,0.00009210197,0.00006010361,0.002875993],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002457937,"threshold_uncertainty_score":0.00822264,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01002808282168576,"score_gpt":0.2415186981674931,"score_spread":0.2314906153458073,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}