{"id":"W2811498819","doi":"10.1021/acs.inorgchem.8b00719","title":"Designing Stability into Thermally Reactive Plumbylenes","year":2018,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"Carleton University","funders":"Deutscher Akademischer Austauschdienst; University of Ottawa; Carleton University","keywords":"Chemistry; Steric effects; Thermal decomposition; Thermal stability; Chemical vapor deposition; Decomposition; Volatility (finance); Torr; Butane; Organic chemistry; Inorganic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001327901,0.0002548375,0.0001290203,0.0001204293,0.0001564704,0.0003394992,0.0002407815,0.0001801059,0.001600065],"category_scores_gemma":[0.0002805657,0.0001590386,0.000113239,0.0001085858,0.0001661934,0.0003120649,0.0003398219,0.0003272566,0.0006250032],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003418299,"about_ca_system_score_gemma":0.000206541,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002975588,"about_ca_topic_score_gemma":0.0008074293,"domain_scores_codex":[0.9998794,0.00001812218,0.000007104056,0.00003524628,0.00002812483,0.00003192327],"domain_scores_gemma":[0.9998891,0.00002629737,0.00002801664,0.00001294794,0.0000217669,0.00002183766],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001266746,0.00002724036,0.0002583198,0.0001073965,0.0000081268,0.00009328505,0.00007205142,0.001005742,0.9894581,0.001444708,0.0001381458,0.007260209],"study_design_scores_gemma":[0.00003485043,0.0004592719,0.0009233974,0.00001048969,0.00001204855,0.0001212006,0.00003912965,0.002130861,0.9866896,0.0002396182,0.009328229,0.00001135656],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9784139,0.001281791,0.008766217,0.0001004413,0.00003591407,0.00009191118,0.000162532,0.0002124328,0.01093481],"genre_scores_gemma":[0.9904359,0.0009034534,0.00456457,0.00006828524,0.00001337109,0.00007764497,0.0001677509,0.0000744748,0.003694501],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001600065,"threshold_uncertainty_score":0.005352736,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0119277558873205,"score_gpt":0.2335937400082576,"score_spread":0.221665984120937,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}