{"id":"W2830631725","doi":"10.1111/php.12973","title":"Triplet Excited States and Singlet Oxygen Production by Analogs of Red Wine Pyranoanthocyanins","year":2018,"lang":"en","type":"article","venue":"Photochemistry and Photobiology","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Fundação para a Ciência e a Tecnologia; Natural Sciences and Engineering Research Council of Canada; Conselho Nacional de Desenvolvimento Científico e Tecnológico; Fundação de Amparo à Pesquisa do Estado de São Paulo","keywords":"Photochemistry; Chemistry; Flash photolysis; Excited state; Triplet state; Singlet fission; Singlet oxygen; Acetonitrile; Chromophore; Singlet state; Trifluoroacetic acid; Phosphorescence; Oxygen; Redox; Molecule; Inorganic chemistry; Organic chemistry; Fluorescence; Kinetics; Atomic physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001746377,0.0003495227,0.0005344409,0.0000321161,0.0002213754,0.00001631112,0.0001776775,0.0002818894,0.0005180793],"category_scores_gemma":[0.000120927,0.0003353394,0.00006367748,0.0001660727,0.001099086,0.00006464513,0.00007460437,0.0002591193,0.0000011726],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002733205,"about_ca_system_score_gemma":0.00003797011,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001088726,"about_ca_topic_score_gemma":0.00001253452,"domain_scores_codex":[0.9982849,0.00002747561,0.0004413973,0.000689113,0.0001035026,0.0004536234],"domain_scores_gemma":[0.9991235,0.0000926776,0.0001606023,0.0003428226,0.0001453844,0.0001350825],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006884729,0.0001248647,0.001274144,0.0004405959,0.000180575,0.000003822631,0.0003794993,2.905894e-7,0.993063,0.000003561291,0.003588192,0.0002529653],"study_design_scores_gemma":[0.001011675,0.0001818245,0.0001709021,0.00007286109,0.00007382834,0.0001538797,0.0002679997,0.0000650069,0.9854699,0.0003891287,0.01180812,0.0003348501],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9942943,0.001204113,0.00002586661,0.0002751856,0.00005291789,0.0001826215,0.0003726284,0.0000798247,0.003512568],"genre_scores_gemma":[0.9971981,0.001003752,0.00004277023,0.00008294272,0.0002574208,0.0001004079,0.0004648096,0.00002321661,0.0008265736],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008219931,"threshold_uncertainty_score":0.9999099,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008830033154371662,"score_gpt":0.2288519192145228,"score_spread":0.2200218860601512,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}