{"id":"W2830631725","doi":"10.1111/php.12973","title":"Triplet Excited States and Singlet Oxygen Production by Analogs of Red Wine Pyranoanthocyanins","year":2018,"lang":"en","type":"article","venue":"Photochemistry and Photobiology","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Fundação para a Ciência e a Tecnologia; Natural Sciences and Engineering Research Council of Canada; Conselho Nacional de Desenvolvimento Científico e Tecnológico; Fundação de Amparo à Pesquisa do Estado de São Paulo","keywords":"Photochemistry; Chemistry; Flash photolysis; Excited state; Triplet state; Singlet fission; Singlet oxygen; Acetonitrile; Chromophore; Singlet state; Trifluoroacetic acid; Phosphorescence; Oxygen; Redox; Molecule; Inorganic chemistry; Organic chemistry; Fluorescence; Kinetics; Atomic physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009202407,0.0001742093,0.0001168978,0.00009235153,0.0001010529,0.0001760092,0.0001140899,0.0001813121,0.0007570205],"category_scores_gemma":[0.0001586663,0.00006907505,0.0001388834,0.00007267579,0.0001228292,0.0001295657,0.0001009731,0.000233811,0.0001300189],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002608723,"about_ca_system_score_gemma":0.00009821191,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005982581,"about_ca_topic_score_gemma":0.0005021579,"domain_scores_codex":[0.9999251,0.00001615235,0.000003987998,0.00001822955,0.0000170428,0.00001955581],"domain_scores_gemma":[0.9999106,0.00001849546,0.00002450664,0.000009661836,0.00001636346,0.00002039602],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005618887,0.000004282113,0.00007837061,0.00000831211,0.000001265205,0.00001473608,0.000006959602,0.00003644513,0.9995909,0.00003604334,0.000006088054,0.0001603243],"study_design_scores_gemma":[0.000009445106,0.0002066079,0.001024024,0.000001635206,0.000003456262,0.00003991999,0.000009875785,0.0005005167,0.9978301,0.00002873895,0.0003436854,0.000002090352],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9989398,0.0001379597,0.0005317871,0.0000120604,0.000005889145,0.000003933941,0.00003332144,0.00001228593,0.0003229424],"genre_scores_gemma":[0.99898,0.00005565964,0.0002966207,0.00001047023,0.000002297133,0.000003287649,0.00009335639,0.000005522531,0.0005528106],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007570205,"threshold_uncertainty_score":0.002532423,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008830033154371662,"score_gpt":0.2288519192145228,"score_spread":0.2200218860601512,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}