{"id":"W2883399833","doi":"10.1021/acs.joc.8b01412","title":"Chemistry Takes a Bath: Reactions in Aqueous Media","year":2018,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Chemistry and Chemical Engineering","field":"Environmental Science","cited_by":125,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Aqueous solution; Aqueous medium; Organic chemistry; Computational chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003114713,0.0001343788,0.0001568993,0.000005013985,0.00005781056,0.00001278387,0.0004810365,0.0001082956,0.01435624],"category_scores_gemma":[0.00036458,0.000101563,0.00006109946,0.0002530636,0.0002363326,0.00008490139,0.00008717569,0.0004824224,0.00005631196],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002363387,"about_ca_system_score_gemma":0.00003154909,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000009877717,"about_ca_topic_score_gemma":0.000004645478,"domain_scores_codex":[0.9990152,0.000008695513,0.0003704673,0.0001121986,0.0002731046,0.0002203857],"domain_scores_gemma":[0.9992819,0.0001285254,0.0001843607,0.0002582906,0.00002047046,0.0001264378],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002389975,0.00004592853,0.000218054,0.00002066184,0.000009274695,0.00001599733,0.0003406905,0.00005774116,0.9979383,1.069973e-7,0.0008502814,0.0004790191],"study_design_scores_gemma":[0.0002844104,0.00000689826,0.0003127308,0.00004985018,0.00002109097,0.000856942,0.0003379852,0.0001156289,0.9929628,0.0001004105,0.004831655,0.0001195616],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9815599,0.0001555753,0.0001235904,0.0003045304,0.00006351982,0.00001881764,0.000001653355,0.00001607976,0.01775632],"genre_scores_gemma":[0.9985309,0.00005432171,0.0001743934,0.00003421969,0.0004839234,6.470229e-7,0.000001238662,0.00001561805,0.0007047932],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01705153,"threshold_uncertainty_score":0.9865448,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004749005809629201,"score_gpt":0.1828248913882198,"score_spread":0.1780758855785906,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}