{"id":"W2884803887","doi":"10.1016/j.poly.2018.07.020","title":"DNA interaction and anticancer evaluation of new palladium(II), platinum(II) and silver(I) complexes based on (Δ)- and (Λ)-1,2–bis-(1H-benzimidazol-2-yl)-1,2-ethanediol enantiomers","year":2018,"lang":"en","type":"article","venue":"Polyhedron","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":17,"is_retracted":false,"has_abstract":false,"ca_institutions":"Royal Victoria Hospital; Institut National de la Recherche Scientifique; McGill University","funders":"Natural Sciences and Engineering Research Council of Canada; Ministry of Higher Education, Egypt","keywords":"Chemistry; Denticity; Molar conductivity; Palladium; Circular dichroism; Chelation; Stereochemistry; Platinum; Proton NMR; Enantiomer; Metal; Crystallography; Protonation; Octahedral molecular geometry; Metal ions in aqueous solution; Inorganic chemistry; Ion; Crystal structure; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007197566,0.000252617,0.0004814942,0.0002330924,0.0002347042,0.00003464719,0.000058016,0.0001018692,0.0005307833],"category_scores_gemma":[0.000280705,0.0001952469,0.00005540136,0.0001415008,0.0003221996,0.0001627339,0.00007945494,0.0001379728,0.000004914138],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005470204,"about_ca_system_score_gemma":0.0001274834,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005037195,"about_ca_topic_score_gemma":0.0001343176,"domain_scores_codex":[0.9982406,0.0001465469,0.0003845514,0.0004166246,0.0005578846,0.0002537784],"domain_scores_gemma":[0.998988,0.0001739878,0.0001983135,0.0002822669,0.000172494,0.0001849322],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00192851,0.000169374,0.01350399,0.0003116904,0.0001321054,0.000001544169,0.002172042,0.00001714625,0.8836175,0.000285874,0.001099566,0.09676067],"study_design_scores_gemma":[0.00831544,0.006878791,0.3185174,0.001561202,0.001296991,0.00009177854,0.0009661977,0.06748536,0.5831031,0.0007016207,0.01032107,0.0007611139],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9927745,0.001192881,0.00005810031,0.001088622,0.0002146667,0.0005260794,0.00001519111,0.00003414144,0.004095852],"genre_scores_gemma":[0.9981643,0.0001619708,0.000633598,0.0003634795,0.0002839584,0.00001308445,0.00002069663,0.00002866062,0.0003302417],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3050134,"threshold_uncertainty_score":0.796194,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.08902134773922876,"score_gpt":0.334397062509269,"score_spread":0.2453757147700402,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}