{"id":"W2885094328","doi":"10.1021/acsomega.8b00775","title":"New Reactions for Old Ions: Cage Rearrangements, Hydrolysis, and Two-Electron Reduction of <i>nido</i>-Decaborane in Neat 1-Ethyl-3-Methylimidazolium Acetate","year":2018,"lang":"en","type":"article","venue":"ACS Omega","topic":"Ionic liquids properties and applications","field":"Chemical Engineering","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Air Force Office of Scientific Research; Canada Research Chairs; Canada Excellence Research Chairs, Government of Canada; Iowa State University","keywords":"Decaborane; Reactivity (psychology); Chemistry; Hydrolysis; Ion; Ionic liquid; Cage; Inorganic chemistry; Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002078241,0.0001526302,0.0002296481,0.0001235287,0.0001044698,0.00002175744,0.0001403193,0.00009181783,0.00001668571],"category_scores_gemma":[0.00007076065,0.0001461626,0.00005391016,0.0004144928,0.00006971111,0.0001953319,0.00004838041,0.0001626342,0.0000106909],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008593822,"about_ca_system_score_gemma":0.00004364639,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001256668,"about_ca_topic_score_gemma":0.00008763702,"domain_scores_codex":[0.9988716,0.00001806805,0.0003702329,0.0003001854,0.0001251706,0.0003147136],"domain_scores_gemma":[0.9993222,0.00005809374,0.00009870616,0.0003401188,0.00009460422,0.00008627785],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009443819,0.00005282739,0.00002380177,0.0000530308,0.00004709743,1.942062e-7,0.000452033,0.0002732736,0.990362,0.003447452,0.001381953,0.003811835],"study_design_scores_gemma":[0.001880542,0.0001953744,0.0001602993,0.00009388782,0.00009625804,0.000009742257,0.000203664,0.003783697,0.9241708,0.001545946,0.06757732,0.0002824733],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9923524,0.000853467,0.002959939,0.001705479,0.0001769128,0.0005529157,0.0000207926,0.00009620802,0.001281877],"genre_scores_gemma":[0.9913733,0.0004087492,0.003733132,0.00005742887,0.000333444,0.0001511253,0.00003636261,0.00003602189,0.003870408],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06619538,"threshold_uncertainty_score":0.5960338,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01335993603268022,"score_gpt":0.2648879650073674,"score_spread":0.2515280289746872,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}