{"id":"W2885094328","doi":"10.1021/acsomega.8b00775","title":"New Reactions for Old Ions: Cage Rearrangements, Hydrolysis, and Two-Electron Reduction of <i>nido</i>-Decaborane in Neat 1-Ethyl-3-Methylimidazolium Acetate","year":2018,"lang":"en","type":"article","venue":"ACS Omega","topic":"Ionic liquids properties and applications","field":"Chemical Engineering","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Air Force Office of Scientific Research; Canada Research Chairs; Canada Excellence Research Chairs, Government of Canada; Iowa State University","keywords":"Decaborane; Reactivity (psychology); Chemistry; Hydrolysis; Ion; Ionic liquid; Cage; Inorganic chemistry; Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001473227,0.0003343382,0.0001979459,0.0001406093,0.0001702739,0.0003003686,0.0004042901,0.0002850515,0.0009617846],"category_scores_gemma":[0.0001980952,0.0001549552,0.0001934635,0.0001075971,0.0003319558,0.0003483192,0.000396003,0.0004472988,0.0002624019],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002583604,"about_ca_system_score_gemma":0.0001786029,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003779201,"about_ca_topic_score_gemma":0.0008347807,"domain_scores_codex":[0.9998705,0.0000155631,0.000009804819,0.00002451297,0.00003277865,0.00004679728],"domain_scores_gemma":[0.9999486,0.00001274409,0.00001179142,0.000009678342,0.000005840777,0.00001125598],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001907484,0.00003241703,0.0002058388,0.0001150341,0.00001358728,0.0001815063,0.0001943998,0.0001450441,0.9939224,0.001132306,0.0001228014,0.003744016],"study_design_scores_gemma":[0.000008628082,0.00007132717,0.0002053828,0.000002357639,0.000003823656,0.00009355825,0.00002279308,0.0001642501,0.9986285,0.00006102659,0.0007339628,0.000004527732],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9920661,0.0006056393,0.00237089,0.0000790597,0.00003349936,0.00002257255,0.00006670255,0.00007520196,0.004680404],"genre_scores_gemma":[0.9964618,0.0004480297,0.00117632,0.00002610361,0.000005531046,0.000013598,0.00008331761,0.00002369069,0.00176167],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009617846,"threshold_uncertainty_score":0.003217459,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01335993603268022,"score_gpt":0.2648879650073674,"score_spread":0.2515280289746872,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}