{"id":"W2885251256","doi":"10.1021/acs.organomet.8b00440","title":"Divergent Reactivity of CO <sub>2</sub> , CO, and Related Substrates at the Nickel Carbon Double Bond of (PC <sub>carbene</sub> P)Ni(II) Pincer Complexes","year":2018,"lang":"en","type":"article","venue":"Organometallics","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Centre National de la Recherche Scientifique; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Chemistry; Carbene; Pincer movement; Reactivity (psychology); Ligand (biochemistry); Nickel; Carbon monoxide; Isocyanide; Moiety; Pincer ligand; Photochemistry; Medicinal chemistry; Double bond; Polymer chemistry; Stereochemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001151833,0.0004393863,0.0002705055,0.0001853337,0.0002358507,0.0005298647,0.000445953,0.0003040577,0.0009920709],"category_scores_gemma":[0.0003546307,0.0001554502,0.0001032123,0.0002389189,0.0004278836,0.0003531781,0.0003678262,0.0004346688,0.0002527066],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004259416,"about_ca_system_score_gemma":0.000163975,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007918198,"about_ca_topic_score_gemma":0.001749934,"domain_scores_codex":[0.9998013,0.00002936084,0.00001283454,0.00005114044,0.00004753298,0.00005771106],"domain_scores_gemma":[0.9998791,0.00002914752,0.00003237654,0.00001600604,0.0000201608,0.00002311284],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005032541,0.00002468739,0.0003583362,0.0001453377,0.00002569848,0.0001853325,0.0001158071,0.000355281,0.9929732,0.0007752044,0.0001169637,0.004420901],"study_design_scores_gemma":[0.000004400769,0.00008796421,0.0003210471,0.000002358106,0.000005292197,0.00008481367,0.00001657466,0.0002555661,0.9985721,0.00002580245,0.0006198944,0.000004161835],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9915931,0.0007691879,0.00120706,0.00003968666,0.00001407207,0.00002017083,0.00009965358,0.00007249068,0.006184623],"genre_scores_gemma":[0.9983819,0.0002463529,0.0004429229,0.00001375936,0.000002108631,0.000009707337,0.0001024007,0.00001700994,0.0007838499],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009920709,"threshold_uncertainty_score":0.003318787,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01542270646157164,"score_gpt":0.2363339784956182,"score_spread":0.2209112720340466,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}