{"id":"W2885384084","doi":"10.1021/acs.jpcc.8b06724","title":"Topochemical Polymerization of Phenylacetylene Macrocycles under Pressure","year":2018,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"Polydiacetylene-based materials and applications","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor; Université Laval","funders":"Alfred P. Sloan Foundation","keywords":"Phenylacetylene; Polymerization; Materials science; Covalent bond; Carbon nanotube; Absorption (acoustics); Photochemistry; Ambient pressure; Alkyne; Thermal decomposition; Nanostructure; Chemical engineering; Chemistry; Nanotechnology; Organic chemistry; Polymer; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001060907,0.0001333546,0.000248693,0.00000749904,0.00006988885,0.0000156104,0.0003914307,0.0000760753,0.0005644378],"category_scores_gemma":[0.00003822433,0.00009113349,0.0001260284,0.00008663459,0.0002947934,0.0000668001,0.00006525529,0.0001699714,0.000005951526],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001926643,"about_ca_system_score_gemma":0.00006250052,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000006094022,"about_ca_topic_score_gemma":1.303585e-7,"domain_scores_codex":[0.9991257,0.00001636153,0.0003354379,0.00009619717,0.0002620381,0.0001642283],"domain_scores_gemma":[0.9989069,0.0001161182,0.0004334957,0.0002977079,0.0001593609,0.00008637903],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001108712,0.0001752516,0.000008087,0.0001012312,0.00006845323,2.197078e-7,0.0001500361,0.00004187161,0.9984072,0.0003683248,0.0001947695,0.0003736519],"study_design_scores_gemma":[0.0003524616,0.00002449556,0.0000187574,0.00005975471,0.0001530176,0.00001934677,0.0001592348,0.000175548,0.9966079,0.001221566,0.001113092,0.00009479607],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9939901,0.0002320132,0.0003013539,0.0003279153,0.00002193836,0.00002260909,0.00004383783,0.00001416284,0.005046078],"genre_scores_gemma":[0.9978692,0.0000280859,0.00008113433,0.00003683348,0.001618769,0.000002044301,0.00000689323,0.00001722136,0.0003398298],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004706248,"threshold_uncertainty_score":0.6180198,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006807460061389192,"score_gpt":0.2436788124951442,"score_spread":0.236871352433755,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}