{"id":"W2885624147","doi":"10.1002/chem.201803471","title":"Chain‐Conformation‐Directed Polymerization Cyclization for Effective Synthesis of Macrocycles in Bulk","year":2018,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"Natural Sciences and Engineering Research Council of Canada; China Scholarship Council","keywords":"Chemistry; Polymerization; Monomer; Supramolecular chemistry; Macromolecule; Ring-opening polymerization; Metal; Stereochemistry; Polymer chemistry; Crystallography; Polymer; Crystal structure; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001234147,0.0003881993,0.0001552985,0.0002134888,0.0001318048,0.00017325,0.0001585249,0.0001865384,0.002409754],"category_scores_gemma":[0.0001671815,0.0001536236,0.0001729293,0.0001305894,0.0001613321,0.0002909259,0.0001998219,0.000463445,0.0006115859],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001721159,"about_ca_system_score_gemma":0.0002198439,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001668065,"about_ca_topic_score_gemma":0.0004494257,"domain_scores_codex":[0.9999114,0.000009881917,0.000006521067,0.00003019008,0.0000209519,0.00002100574],"domain_scores_gemma":[0.9999257,0.00001565173,0.00002319102,0.000009957684,0.000009325322,0.00001614584],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002896172,0.00003131485,0.00004529082,0.0000776592,0.000004906705,0.00005374383,0.00002305426,0.0006994462,0.989355,0.001082835,0.0001630644,0.008434659],"study_design_scores_gemma":[0.00002058669,0.0003957584,0.0003308715,0.000008021524,0.000009699383,0.00009158514,0.000005476635,0.002576394,0.9909198,0.0002036233,0.005427902,0.00001027523],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8950797,0.003499754,0.08468884,0.0002230437,0.0001522108,0.0002754976,0.0003838145,0.0009087453,0.01478835],"genre_scores_gemma":[0.9648224,0.001097327,0.03029988,0.00007718423,0.00002955295,0.0001417238,0.0002495501,0.00009220897,0.003190032],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002409754,"threshold_uncertainty_score":0.008061409,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00437043457407903,"score_gpt":0.2185026377921564,"score_spread":0.2141322032180774,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}