{"id":"W2885642087","doi":"10.1021/acs.analchem.8b03023","title":"Self-Inhibitory Electron Transfer of the Co(III)/Co(II)-Complex Redox Couple at Pristine Carbon Electrode","year":2018,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Division of Chemistry; Alberta Innovates; Centre National de la Recherche Scientifique; Alberta Innovates - Technology Futures; Natural Sciences and Engineering Research Council of Canada; Xiamen University; National Science Foundation","keywords":"Chemistry; Redox; Cyclic voltammetry; Electron transfer; Scanning electrochemical microscopy; Voltammetry; Adsorption; Electrochemistry; Aqueous solution; Glassy carbon; Inorganic chemistry; Dissolution; Photochemistry; Electrode; Analytical Chemistry (journal); Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001514799,0.0003577384,0.0005149649,0.00002091896,0.0003486414,0.00002022061,0.0006634546,0.0003121595,0.001744814],"category_scores_gemma":[0.00005762297,0.0002818232,0.0004262518,0.0004686244,0.0004956239,0.00002803949,0.0001070089,0.0005528472,0.0000243528],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003088579,"about_ca_system_score_gemma":0.0001463021,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000325741,"about_ca_topic_score_gemma":0.00001669138,"domain_scores_codex":[0.9973843,0.00001567065,0.0006645462,0.0006637486,0.0005721303,0.0006996352],"domain_scores_gemma":[0.9983951,0.000100774,0.0001442886,0.000960891,0.0001787474,0.0002202328],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006711169,0.0003030428,0.0007851214,0.000131425,0.0002064763,9.81393e-7,0.00004656833,0.00000113735,0.9940099,0.0002210098,0.004202875,0.00002439141],"study_design_scores_gemma":[0.0004720605,0.0000354675,0.00006053328,0.00002454128,0.0003327831,0.00001631485,0.00001344507,0.005680912,0.9573999,0.0001927996,0.03546297,0.0003082549],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8906525,0.0001141065,0.00003129268,0.0006120035,0.000006115795,0.0000768133,0.00002611508,0.0001164222,0.1083646],"genre_scores_gemma":[0.9898692,0.00003593734,0.00005696539,0.0001241746,0.0006173489,0.00003249022,0.0001583777,0.00004251804,0.009062974],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.09930167,"threshold_uncertainty_score":0.9999634,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007755946823549469,"score_gpt":0.2462178766780504,"score_spread":0.2384619298545009,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}