{"id":"W2885730843","doi":"10.1039/c8nr04002h","title":"Room-temperature surface-assisted reactivity of a melanin precursor: silver metal–organic coordination<i>versus</i>covalent dimerization on gold","year":2018,"lang":"en","type":"article","venue":"Nanoscale","topic":"Surface Chemistry and Catalysis","field":"Engineering","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"Institut National de la Recherche Scientifique","funders":"Fonds de recherche du Québec – Nature et technologies; Australian Research Council; Natural Sciences and Engineering Research Council of Canada; University of Toronto; Government of Jiangxi Province; Canada Research Chairs; Government of Ontario; Compute Canada","keywords":"Scanning tunneling microscope; Molecule; Supramolecular chemistry; Intermolecular force; Reactivity (psychology); Polymerization; Covalent bond; Redox; Density functional theory; Catechol; Materials science; Dimer; Chemistry; Substrate (aquarium); Metal; Photochemistry; Nanotechnology; Computational chemistry; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009055414,0.0001919024,0.0001186847,0.00009202434,0.0001081061,0.0001706987,0.0002342714,0.0002003821,0.0008188077],"category_scores_gemma":[0.0001686333,0.00009829248,0.00009718285,0.00009191611,0.0001635264,0.0001149556,0.00011554,0.0002329774,0.0001791675],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002568881,"about_ca_system_score_gemma":0.00009946732,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00134388,"about_ca_topic_score_gemma":0.001981525,"domain_scores_codex":[0.9999219,0.000007141386,0.000003909248,0.00002002817,0.00002244915,0.0000245542],"domain_scores_gemma":[0.9999352,0.00001576918,0.00001923272,0.000009213233,0.00001048541,0.00001022902],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004977567,0.00001142393,0.0001718662,0.00002369928,0.000004032547,0.00005429255,0.00004135428,0.0001348164,0.9986339,0.00004554783,0.00004210988,0.0007871375],"study_design_scores_gemma":[0.000005477376,0.0001161159,0.002083433,0.000002342941,0.000004000072,0.0000369843,0.00002457779,0.001512143,0.9959125,0.00001380041,0.0002846206,0.000003984055],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9986975,0.000107177,0.0003082192,0.00001752012,0.000004827448,0.000005372142,0.000032331,0.00002315035,0.0008038526],"genre_scores_gemma":[0.9991346,0.00007945687,0.0003580634,0.000007827646,0.000001605272,0.000003550223,0.00003244652,0.000006574438,0.000375853],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00134388,"threshold_uncertainty_score":0.002739251,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01065944442324304,"score_gpt":0.2198149674920855,"score_spread":0.2091555230688424,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}