{"id":"W2887671914","doi":"10.1139/cjc-2018-0303","title":"Synthesis and photophysical evaluation of new fluorescent 7-arylethynyl-7-deazaadenosine analogs","year":2018,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Click Chemistry and Applications","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Sonogashira coupling; Fluorescence; Deoxyadenosine; 2-Norbornyl cation; Photochemistry; Domino; Combinatorial chemistry; Stereochemistry; Organic chemistry; Palladium; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002606587,0.0001452361,0.0002553194,0.00003397957,0.0000935623,0.00002919907,0.0002753922,0.000144245,0.003693698],"category_scores_gemma":[0.0004895963,0.000148551,0.0001013427,0.0001397127,0.0003728759,0.00006542218,0.0000168092,0.0002273833,0.000004371175],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001632199,"about_ca_system_score_gemma":0.001548804,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005851036,"about_ca_topic_score_gemma":0.0002144076,"domain_scores_codex":[0.9988526,0.0000101636,0.0004188291,0.0001721339,0.0003276675,0.0002186102],"domain_scores_gemma":[0.9980938,0.00007842991,0.0003277805,0.0002859206,0.0005092375,0.0007048705],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001944327,0.00003362921,0.00131688,0.00009926905,0.00006846109,0.000007659028,0.0002586064,0.00000497046,0.9838405,0.0000124828,0.005068914,0.009269148],"study_design_scores_gemma":[0.0004486508,0.000009919866,0.00049399,0.0001803961,0.0001702404,0.000127993,0.0002381299,0.0001339599,0.9919364,0.0005108165,0.005614869,0.0001345625],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9902536,0.0005341465,0.00002146992,0.0004959733,0.00003061706,0.00002941261,0.00005186298,0.000004991418,0.008577919],"genre_scores_gemma":[0.9985183,0.00001710448,0.0001492998,0.00002890318,0.000907219,0.000003841696,0.00001089202,0.00001524608,0.0003491632],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009134585,"threshold_uncertainty_score":0.9972171,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02587713583574961,"score_gpt":0.2657629815951447,"score_spread":0.2398858457593951,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}