{"id":"W2887765429","doi":"10.1038/s42004-018-0042-y","title":"Catalytic N-modification of α-amino acids and small peptides with phenol under bio-compatible conditions","year":2018,"lang":"en","type":"article","venue":"Communications Chemistry","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Fonds Québécois de la Recherche sur la Nature et les Technologies; Natural Sciences and Engineering Research Council of Canada; Consejo Nacional de Ciencia y Tecnología; McGill University","keywords":"Chemistry; Phenol; Amino acid; Organic chemistry; Biomolecule; Racemization; Catalysis; Surface modification; Combinatorial chemistry; Reagent; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006848688,0.000110168,0.0001330728,0.0000192534,0.0001554742,0.00001833302,0.0003963736,0.00008909052,0.00002424293],"category_scores_gemma":[0.00004966673,0.0001007106,0.00004752308,0.0001386731,0.0007229624,0.000004422309,0.0001829944,0.00006669091,0.00000474818],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001313524,"about_ca_system_score_gemma":0.00004534931,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003169121,"about_ca_topic_score_gemma":0.00003478848,"domain_scores_codex":[0.999406,0.00001931565,0.0001906286,0.000208992,0.00006295861,0.0001120705],"domain_scores_gemma":[0.998388,0.00003688573,0.0001205833,0.001214276,0.000177782,0.00006248893],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001013431,0.0001057097,0.002536839,0.00002817915,0.00007655126,4.131253e-8,0.00004095201,0.000003282871,0.9963053,0.000116216,0.0001025343,0.0006741953],"study_design_scores_gemma":[0.0002022594,0.00003184766,0.003076506,0.0000303335,0.00008533229,0.000007280545,0.0002935923,0.0002661351,0.993809,0.0001580823,0.001901223,0.0001384327],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9908135,0.0005414086,0.0008932863,0.0003712968,0.000003671023,0.00006666264,0.00004902222,0.00001318429,0.007247953],"genre_scores_gemma":[0.9962866,0.0002289442,0.00225413,0.00003989049,0.0000433295,0.00002964815,0.0006684837,0.00001305165,0.0004359782],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006811975,"threshold_uncertainty_score":0.4106859,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0268231176582208,"score_gpt":0.2747368381419021,"score_spread":0.2479137204836813,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}