{"id":"W2888767132","doi":"10.1002/cphc.201800683","title":"A Quadrupole‐Central‐Transition <sup>59</sup>Co NMR Study of Cobalamins in Solution","year":2018,"lang":"en","type":"article","venue":"ChemPhysChem","topic":"Porphyrin Metabolism and Disorders","field":"Biochemistry, Genetics and Molecular Biology","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa; Queen's University","funders":"Canada Foundation for Innovation; Ontario Innovation Trust","keywords":"Quadrupole; Chemistry; Nuclear magnetic resonance spectroscopy; Transition metal; Crystallography; Physical chemistry; Physics; Atomic physics; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000131244,0.0002121694,0.0002387863,0.0001837022,0.0003993593,0.0002382617,0.0002605059,0.0003293995,0.0008909472],"category_scores_gemma":[0.0002988683,0.0001128232,0.00008020287,0.0001428886,0.0004330581,0.0001908962,0.0002135479,0.0004923025,0.0001655478],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004522109,"about_ca_system_score_gemma":0.0002872561,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.004294047,"about_ca_topic_score_gemma":0.002460619,"domain_scores_codex":[0.9998919,0.00001520838,0.0000035266,0.00002695734,0.00004249693,0.00001984586],"domain_scores_gemma":[0.9998479,0.00004440243,0.00002724255,0.00000852134,0.00005101951,0.00002083841],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002082124,0.000003351618,0.00007818027,0.00001847367,0.000001788465,0.00002067243,0.00001511881,0.00004217799,0.9992567,0.00002724213,0.00002006715,0.0004953776],"study_design_scores_gemma":[0.000006994761,0.00008057337,0.001099537,0.000003411429,0.00000628693,0.00008717029,0.00003472253,0.000739629,0.9972076,0.00002469674,0.0007035306,0.000005795427],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9929108,0.001226848,0.004326767,0.0001837237,0.00001647852,0.00001564049,0.00008971637,0.00003294766,0.001197041],"genre_scores_gemma":[0.994954,0.0004712668,0.003410829,0.00005394685,0.00001147757,0.00001122879,0.00009794201,0.00001284433,0.0009763255],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004294047,"threshold_uncertainty_score":0.008538067,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009499249859393124,"score_gpt":0.2534486674382538,"score_spread":0.2439494175788607,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}