{"id":"W2890916363","doi":"10.1039/c8cc06446f","title":"A tetrameric perylene diimide non-fullerene acceptor <i>via</i> unprecedented direct (hetero)arylation cross-coupling reactions","year":2018,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Fullerene Chemistry and Applications","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"Calgary Laboratory Services; University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Canada Foundation for Innovation; Alberta Innovates - Technology Futures; University of Calgary","keywords":"Diimide; Perylene; Fullerene; Acceptor; Coupling (piping); Photochemistry; Chemistry; Materials science; Molecule; Physics; Condensed matter physics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001473379,0.0003869562,0.0003590821,0.00006958217,0.001009586,0.0001748381,0.001788107,0.0003262745,0.001559122],"category_scores_gemma":[0.0003058923,0.0004271929,0.0002456649,0.00065238,0.0009955425,0.0002819771,0.0006173966,0.0007046306,0.0004000008],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002404119,"about_ca_system_score_gemma":0.0000839459,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001337206,"about_ca_topic_score_gemma":0.0000206092,"domain_scores_codex":[0.9977833,0.000017201,0.0007702771,0.0006478744,0.0002811476,0.0005001925],"domain_scores_gemma":[0.9950668,0.0005565152,0.0003354969,0.003354386,0.0004047516,0.0002820878],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003105119,0.0004178175,0.001270147,0.00005921723,0.00007346392,2.890265e-7,0.0001377714,0.0000387655,0.9956635,0.00006564853,0.001110774,0.001131532],"study_design_scores_gemma":[0.0005329112,0.00001338915,0.0003133443,0.00009115105,0.00007178986,0.00001693652,0.000117801,0.00987042,0.9517657,0.0002694379,0.03646362,0.0004734573],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8794136,0.0002703592,0.001329129,0.001190964,0.00008519343,0.0001986098,0.0001061279,0.0006229925,0.116783],"genre_scores_gemma":[0.9906981,0.0002370615,0.004259773,0.00013602,0.0004986783,0.0004592783,0.001252928,0.00007690836,0.002381233],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1144018,"threshold_uncertainty_score":0.999818,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02620454260981728,"score_gpt":0.3100739564710435,"score_spread":0.2838694138612262,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}