{"id":"W2891483223","doi":"10.1002/ejic.201800654","title":"Isolable Adducts of Tertiary Amines and Dinitrogen Trioxide","year":2018,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"Chemical Reactions and Mechanisms","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; DABCO; Adduct; Medicinal chemistry; Octane; Amine gas treating; Tertiary amine; Dichloromethane; Toluene; Organic chemistry; Solvent","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002319795,0.0001599808,0.0002548802,0.000025663,0.00004991278,0.00002224429,0.0002851347,0.00005238988,0.001909532],"category_scores_gemma":[0.0003276714,0.0001391944,0.00009958068,0.00009525719,0.0001420277,0.00009510667,0.0001227086,0.0002717968,0.00001774823],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003931072,"about_ca_system_score_gemma":0.00005813269,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002263494,"about_ca_topic_score_gemma":2.087375e-7,"domain_scores_codex":[0.9988682,0.00001757072,0.0005714258,0.0001620803,0.0001937421,0.0001869243],"domain_scores_gemma":[0.9987527,0.0000645469,0.0004793885,0.000253206,0.0002606876,0.0001895377],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005130189,0.00007251974,0.0002810644,0.0001145662,0.00006464258,0.00004952717,0.0001069469,5.548631e-8,0.9955289,0.000003967371,0.001266008,0.002460436],"study_design_scores_gemma":[0.0007467183,0.00004634384,0.0001150925,0.0001541988,0.00006278042,0.0007898836,0.0002598519,0.000004600155,0.9868602,0.00005836305,0.01077084,0.0001311853],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9780828,0.0005871592,0.00008173187,0.00006238278,0.00007158945,0.00001256188,0.00001058844,0.00001738003,0.02107381],"genre_scores_gemma":[0.9968916,0.0001722095,0.0007606957,0.00004161657,0.0007819056,1.917548e-7,0.000003308126,0.00003790874,0.001310531],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01976328,"threshold_uncertainty_score":0.9990029,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008082238784803556,"score_gpt":0.2045621154381779,"score_spread":0.1964798766533743,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}