{"id":"W2891483223","doi":"10.1002/ejic.201800654","title":"Isolable Adducts of Tertiary Amines and Dinitrogen Trioxide","year":2018,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"Chemical Reactions and Mechanisms","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; DABCO; Adduct; Medicinal chemistry; Octane; Amine gas treating; Tertiary amine; Dichloromethane; Toluene; Organic chemistry; Solvent","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001607154,0.0003700338,0.0002086202,0.0001342429,0.0001276296,0.00009116749,0.000295019,0.0001798832,0.001888798],"category_scores_gemma":[0.0001930373,0.0001493632,0.0001409435,0.0001006784,0.0001293446,0.0001263278,0.0002229391,0.0002973033,0.0004783351],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002190829,"about_ca_system_score_gemma":0.0001825432,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009495043,"about_ca_topic_score_gemma":0.002847879,"domain_scores_codex":[0.999879,0.00001585379,0.000005782879,0.00002745644,0.00003796647,0.00003380307],"domain_scores_gemma":[0.9999079,0.00002092645,0.00002390974,0.00001318831,0.0000160107,0.00001813231],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003816486,0.000007689493,0.00007358237,0.00002414999,0.000003584257,0.00003387468,0.00001665456,0.00008880013,0.9989631,0.00004829061,0.00002901777,0.0006732205],"study_design_scores_gemma":[0.000003316839,0.00009060144,0.000321691,0.000001458492,0.000002855806,0.00003975369,0.000005814144,0.0001921271,0.998676,0.00001695298,0.000647312,0.000002040869],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9887592,0.0004417041,0.006513862,0.00003981487,0.00003091399,0.0000342835,0.0002136263,0.0001347322,0.003831947],"genre_scores_gemma":[0.9879522,0.0004596496,0.005104479,0.0000344422,0.000008324655,0.00002394351,0.0005805182,0.00006801949,0.005768394],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001888798,"threshold_uncertainty_score":0.006318688,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008082238784803556,"score_gpt":0.2045621154381779,"score_spread":0.1964798766533743,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}