{"id":"W2892111982","doi":"10.1002/cctc.201801039","title":"Ru‐Catalyzed Transfer Hydrogenation of Nitriles, Aromatics, Olefins, Alkynes and Esters","year":2018,"lang":"en","type":"article","venue":"ChemCatChem","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":59,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa; Regional Municipality of Niagara; Brock University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Transfer hydrogenation; Isomerization; Ruthenium; Catalysis; Phosphine; Olefin fiber; Selectivity; Noyori asymmetric hydrogenation; Organic chemistry; Pyrazole; Solvent; Ligand (biochemistry)","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001611085,0.0002686183,0.0002078623,0.0001354977,0.0001016168,0.0001805165,0.0003664243,0.0002427431,0.001244875],"category_scores_gemma":[0.0001949168,0.000109708,0.0001788732,0.00008557305,0.0001559737,0.0002667338,0.000243613,0.0002645714,0.0003726887],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001907573,"about_ca_system_score_gemma":0.0001093021,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002660415,"about_ca_topic_score_gemma":0.0006261268,"domain_scores_codex":[0.9998983,0.00001833432,0.000006714608,0.00001587909,0.00002768148,0.00003309083],"domain_scores_gemma":[0.9999545,0.00001089935,0.00001072091,0.000008812165,0.000006283899,0.000008810451],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007796597,0.00003706837,0.00009829165,0.0001149237,0.00001743556,0.0001893946,0.00004681603,0.0003863059,0.9913243,0.0004173889,0.0001161623,0.007173855],"study_design_scores_gemma":[0.00001079443,0.00007658625,0.000163575,0.000002407549,0.000006467246,0.00008653236,0.000006249467,0.0004430655,0.9979849,0.00002368173,0.001192942,0.000002817603],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9814172,0.001535808,0.008821582,0.00008836843,0.00005279851,0.00004778526,0.0001251941,0.0001142481,0.007796915],"genre_scores_gemma":[0.9945387,0.0006625668,0.002135799,0.00001280156,0.000008918179,0.0000110603,0.0001099331,0.0000182052,0.002502091],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001244875,"threshold_uncertainty_score":0.004164517,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009678036934846377,"score_gpt":0.2192608581803685,"score_spread":0.2095828212455221,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}