{"id":"W2893591278","doi":"10.71781/11336","title":"Synthèse stéréosélective de centres tertiaires et quaternaires par voie radicalaire et leur application à la synthèse d’analogues de nucléosides et de polypropionate","year":2017,"lang":"fr","type":"dissertation","venue":"Papyrus : Institutional Repository (Université de Montréal)","topic":"Inorganic and Organometallic Chemistry","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Medicinal chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003719257,0.0004236608,0.0002429401,0.0002098865,0.0002033748,0.0003165736,0.000310177,0.0004979111,0.005424357],"category_scores_gemma":[0.0003673592,0.0001949475,0.0004022164,0.0002552981,0.0002639085,0.0005977657,0.0002360903,0.0009542793,0.00117723],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003540693,"about_ca_system_score_gemma":0.0003873099,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007045936,"about_ca_topic_score_gemma":0.0013923,"domain_scores_codex":[0.9998012,0.00003224657,0.00001050896,0.00005723377,0.00005781396,0.00004103644],"domain_scores_gemma":[0.999838,0.0000379259,0.00004317129,0.0000252992,0.00003863521,0.0000170458],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002050058,0.000081474,0.0001549955,0.000544758,0.00002505796,0.0001489339,0.000115342,0.0007909495,0.9716704,0.002772012,0.0005949921,0.02289603],"study_design_scores_gemma":[0.00002705051,0.0009895157,0.0003784594,0.00002627698,0.00002098691,0.0002007163,0.00004119097,0.0005389668,0.9698495,0.0003340256,0.02756543,0.00002780261],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"other","genre_scores_codex":[0.8457709,0.02612217,0.07608377,0.0009617569,0.000918925,0.0005464259,0.001107402,0.0004331744,0.04805555],"genre_scores_gemma":[0.9279155,0.01263864,0.03191085,0.0005146044,0.00009245383,0.0002137125,0.0006276607,0.0001356467,0.02595095],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.005424357,"threshold_uncertainty_score":0.01814628,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004284317790309905,"score_gpt":0.1996162235882489,"score_spread":0.195331905797939,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}