{"id":"W2894749690","doi":"10.1002/anie.201810222","title":"Synthesis of the <i>Campylobacter jejuni</i> 81<b>‐</b>176 Strain Capsular Polysaccharide Repeating Unit Reveals the Absolute Configuration of its <i>O</i>‐Methyl Phosphoramidate Motif","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":31,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Alberta Glycomics Centre","keywords":"Campylobacter jejuni; Stereochemistry; Absolute configuration; Stereocenter; Phosphoramidate; Chemistry; Biology; Biochemistry; Bacteria; Genetics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001008292,0.0004100148,0.0001281189,0.0002290297,0.0001689855,0.0001520891,0.0002401911,0.0002240142,0.002289943],"category_scores_gemma":[0.0001840525,0.0000978271,0.0001752472,0.0003203303,0.0001610599,0.0002333883,0.0002212847,0.000425482,0.0008474805],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002520062,"about_ca_system_score_gemma":0.0006057327,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001010894,"about_ca_topic_score_gemma":0.001284323,"domain_scores_codex":[0.9999127,0.000009046676,0.000004952076,0.00001905844,0.00002373597,0.00003043587],"domain_scores_gemma":[0.9999394,0.000007386556,0.00001548726,0.00001184274,0.00001210933,0.00001362418],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008091074,0.00004543817,0.0001547968,0.0001493179,0.000006295499,0.0002538856,0.00004222913,0.0006633677,0.9791752,0.001156369,0.0003154642,0.01795673],"study_design_scores_gemma":[0.00001076332,0.0005237476,0.001137476,0.00001412323,0.00001243655,0.0003522676,0.00003245852,0.000518917,0.9819207,0.0003639411,0.01509357,0.00001966671],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9042701,0.002089762,0.04125417,0.0003513477,0.0001671898,0.0003375755,0.002159166,0.0004072229,0.04896346],"genre_scores_gemma":[0.9624536,0.002058133,0.02560933,0.0001318297,0.00001515469,0.00007144875,0.002065006,0.00008016851,0.007515247],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002289943,"threshold_uncertainty_score":0.007660627,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01724415272832842,"score_gpt":0.2458634726030745,"score_spread":0.2286193198747461,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}