{"id":"W2895007558","doi":"10.1021/jacs.8b06156","title":"Protonation of a Cobalt Phenylazopyridine Complex at the Ligand Yields a Proton, Hydride, and Hydrogen Atom Transfer Reagent","year":2018,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Division of Chemistry; Natural Sciences and Engineering Research Council of Canada; Stanford University","keywords":"Chemistry; Hydride; Protonation; Hydrogen atom; Exergonic reaction; Hydrogen bond; Bond-dissociation energy; Ligand (biochemistry); Photochemistry; Proton affinity; Reactivity (psychology); Dissociation (chemistry); Medicinal chemistry; Crystallography; Hydrogen; Physical chemistry; Molecule; Catalysis; Organic chemistry; Ion","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009703996,0.0001618829,0.0001860403,0.0000514377,0.0001447558,0.0002116576,0.0002999711,0.0002190112,0.001361408],"category_scores_gemma":[0.0001399749,0.0001000354,0.0001100828,0.00008852727,0.0001941583,0.0001458889,0.0002015329,0.0004300566,0.0002604751],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006491656,"about_ca_system_score_gemma":0.0003488295,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001806842,"about_ca_topic_score_gemma":0.00235209,"domain_scores_codex":[0.9999272,0.000004148952,0.000002486195,0.00001563345,0.00001982889,0.00003075992],"domain_scores_gemma":[0.9999536,0.0000100068,0.000009431102,0.000005929318,0.000006223503,0.00001485364],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001881651,0.00003621721,0.0004396679,0.000113658,0.00001065707,0.0001274075,0.00003683129,0.001040008,0.9936876,0.0009228548,0.0003808572,0.003016148],"study_design_scores_gemma":[0.00004112954,0.0002277135,0.001094015,0.000003340154,0.000007119975,0.0001167158,0.0000228084,0.004977095,0.9916963,0.0001093536,0.001695005,0.000009374065],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9901069,0.0002467771,0.005603487,0.0001489658,0.00003378714,0.00002781831,0.0001275317,0.0001987104,0.003505914],"genre_scores_gemma":[0.9981476,0.00007379655,0.0009692814,0.00001689251,0.000002192692,0.000007823279,0.00006513585,0.00001191452,0.0007055194],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001806842,"threshold_uncertainty_score":0.004710078,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02030940607661323,"score_gpt":0.2622745708216399,"score_spread":0.2419651647450267,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}