{"id":"W2895846352","doi":"10.1039/c8dt03286f","title":"Stoichiometric control: 8- and 10-coordinate Ln(hfac)3(bpy) and Ln(hfac)3(bpy)2 complexes of the early lanthanides La–Sm","year":2018,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"Division of Graduate Education; Division of Chemistry; Natural Sciences and Engineering Research Council of Canada","keywords":"Lanthanide; Stoichiometry; Crystallography; Chemistry; Physical chemistry; Materials science; Ion","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001758088,0.0003650556,0.0001970736,0.0001033887,0.0001415573,0.0002655314,0.0004478818,0.000257454,0.001811076],"category_scores_gemma":[0.0003668682,0.0001880307,0.00007448254,0.0001909253,0.0002505883,0.0002184752,0.0002056781,0.0003064563,0.0004229604],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004660571,"about_ca_system_score_gemma":0.0002411539,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009291866,"about_ca_topic_score_gemma":0.002121027,"domain_scores_codex":[0.9997552,0.00003010478,0.00001884308,0.00008224011,0.00006791817,0.00004563395],"domain_scores_gemma":[0.999866,0.00002256608,0.00004274805,0.0000190095,0.00003188308,0.00001777391],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001667194,0.00002495981,0.0001306827,0.00006172001,0.000004216128,0.00002031081,0.00003118909,0.0001038049,0.9976009,0.0001325616,0.0001122117,0.001610755],"study_design_scores_gemma":[0.0000187003,0.000130676,0.0004639902,0.000002407001,0.000004559573,0.00003206992,0.00001667664,0.0004090504,0.9969523,0.00001772716,0.001948872,0.000002960041],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9904971,0.0004022316,0.002932027,0.00006026018,0.00004157569,0.00007175645,0.0003674433,0.0001716158,0.005455912],"genre_scores_gemma":[0.9897602,0.0003738459,0.005093748,0.00005423696,0.00001155906,0.0001461535,0.0003335684,0.00008151402,0.004145012],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001811076,"threshold_uncertainty_score":0.006058693,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01261908950571508,"score_gpt":0.2302316644556338,"score_spread":0.2176125749499187,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}