{"id":"W2896249594","doi":"10.1021/jacs.8b09440","title":"Molecular-Scale Ligand Effects in Small Gold–Thiolate Nanoclusters","year":2018,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Nanocluster Synthesis and Applications","field":"Materials Science","cited_by":134,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"Air Force Office of Scientific Research; Agència de Gestió d'Ajuts Universitaris i de Recerca; Natural Sciences and Engineering Research Council of Canada; Ministerio de Economía y Competitividad; Ministry of Education - Singapore","keywords":"Chemistry; Nanoclusters; Ligand (biochemistry); Molecule; Small molecule; Intermolecular force; Chemical physics; Crystallography; Nanotechnology; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003968961,0.000121727,0.000305676,0.00001525397,0.00006078019,0.00004491849,0.0006383365,0.00004587545,0.000008258939],"category_scores_gemma":[0.00007086828,0.00007758348,0.0003183852,0.0003403191,0.000494241,0.00006143446,0.0001839139,0.0002049499,0.00001637798],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001142629,"about_ca_system_score_gemma":0.00005712121,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004477871,"about_ca_topic_score_gemma":0.000007359049,"domain_scores_codex":[0.9989542,0.00007568484,0.0003498663,0.0001627993,0.0002020976,0.0002553293],"domain_scores_gemma":[0.9988937,0.000150179,0.0005076685,0.0002683724,0.00008590362,0.00009412405],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002275897,0.00005756839,0.000619671,0.000009528171,0.00001170947,0.000001282522,0.0004132059,0.000006136227,0.9956723,0.00001705143,0.001448093,0.001720722],"study_design_scores_gemma":[0.0002815643,0.00006021921,0.00175337,0.0000714135,0.00002749006,0.00002699766,0.000150063,0.0001226201,0.9962435,0.0003742836,0.0007858753,0.0001025383],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9964194,0.00006412713,0.0008678387,0.002233404,0.0001717577,0.00009976843,0.000001990635,0.000009941506,0.0001318116],"genre_scores_gemma":[0.9901738,0.00001386444,0.007445532,0.002100415,0.0002117308,0.000005487827,1.04463e-7,0.00001400323,0.00003508164],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006577693,"threshold_uncertainty_score":0.3163762,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006704371893934873,"score_gpt":0.2342341831158213,"score_spread":0.2275298112218865,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}