{"id":"W2897564726","doi":"10.1002/anie.201809275","title":"Electrophilic Phosphonium Cation‐Mediated Phosphane Oxide Reduction Using Oxalyl Chloride and Hydrogen","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":53,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Industry Canada; Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Deutsche Forschungsgemeinschaft","keywords":"Heterolysis; Electrophile; Phosphonium; Chemistry; Oxalyl chloride; Oxide; Lewis acids and bases; Frustrated Lewis pair; Metal; Medicinal chemistry; Decomposition; Catalysis; Inorganic chemistry; Combinatorial chemistry; Polymer chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001767723,0.0003449139,0.0001824837,0.0001286872,0.0001342722,0.0002081552,0.0003845998,0.0002477966,0.001054413],"category_scores_gemma":[0.0001157475,0.0001838976,0.0001765368,0.0001176314,0.0001700852,0.0003090974,0.0004676128,0.0003245481,0.0003675293],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001581989,"about_ca_system_score_gemma":0.0001506362,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002687028,"about_ca_topic_score_gemma":0.0005246779,"domain_scores_codex":[0.9998788,0.00001926121,0.00001142479,0.00002420436,0.00003067512,0.00003568347],"domain_scores_gemma":[0.9999695,0.00000551144,0.000009510853,0.000004939038,0.000004144655,0.000006332736],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004977158,0.00001726299,0.00006013529,0.00008961363,0.000007308009,0.00008867236,0.00002998828,0.00007581295,0.9974211,0.0002868303,0.00006599469,0.00180749],"study_design_scores_gemma":[0.00001223471,0.00009580297,0.0002177499,0.000002236187,0.000005607792,0.0001038801,0.000007964679,0.0003045408,0.9980107,0.00002221672,0.001213728,0.000003337811],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9818272,0.0009873675,0.009293944,0.0001131847,0.00004987658,0.0000537484,0.0001414508,0.0001765306,0.007356789],"genre_scores_gemma":[0.9938524,0.0003953131,0.003189363,0.00002793865,0.000006563598,0.00001439109,0.0001183105,0.00001803196,0.002377788],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001054413,"threshold_uncertainty_score":0.003527343,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01103359923896397,"score_gpt":0.242707019583409,"score_spread":0.231673420344445,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}