{"id":"W2897800006","doi":"10.1039/c8ob02063a","title":"Stereoselective synthesis of <i>E</i>-3-(arylmethylidene)-5-(alkyl/aryl)-2(3<i>H</i>)-furanones by sequential hydroacyloxylation-Mizoroki–Heck reactions of iodoalkynes","year":2018,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation","keywords":"Chemistry; Stereoselectivity; Aryl; Alkyl; Regioselectivity; Heck reaction; Stereochemistry; Organic chemistry; Combinatorial chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002627309,0.0006591385,0.0008405932,0.00008947653,0.0002540957,0.0000460441,0.0008183719,0.0005831051,0.01066081],"category_scores_gemma":[0.0009036303,0.0007444215,0.0004154677,0.001073285,0.001121619,0.0001993999,0.0002677335,0.0004510495,0.00007528037],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003260763,"about_ca_system_score_gemma":0.0004495766,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001978044,"about_ca_topic_score_gemma":0.00001144674,"domain_scores_codex":[0.9963065,0.00005214728,0.001236838,0.001010056,0.0007644828,0.0006299482],"domain_scores_gemma":[0.9961907,0.0003130943,0.001083563,0.001393428,0.0007369844,0.0002822399],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009505139,0.0005008468,0.0006566913,0.0006910715,0.0006295764,0.00001231645,0.0001838543,3.884196e-7,0.9958124,0.00001037112,0.00084323,0.0005642052],"study_design_scores_gemma":[0.0007392969,0.00003649927,0.00004986609,0.0002570144,0.0004029628,0.0001562619,0.0004799064,0.0000658708,0.9944762,0.0001422177,0.002549243,0.000644639],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9503099,0.0007531557,0.01056488,0.0003151066,0.0001841585,0.0002275262,0.0009210604,0.0003232572,0.0364009],"genre_scores_gemma":[0.99607,0.0001024071,0.0007529565,0.00002370612,0.0003414885,0.00003992769,0.0002575587,0.0001638283,0.00224814],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04576004,"threshold_uncertainty_score":0.9995007,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007095785288269043,"score_gpt":0.2306195305669611,"score_spread":0.2235237452786921,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}