{"id":"W2897906428","doi":"10.1021/acs.inorgchem.8b02109","title":"Characterization of Oxo-Bridged Iron Amino-bis(phenolate) Complexes Formed Intentionally or in Situ: Mechanistic Insight into Epoxide Deoxygenation during the Coupling of CO<sub>2</sub> and Epoxides","year":2018,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":31,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University; Memorial University of Newfoundland","funders":"Natural Sciences and Engineering Research Council of Canada; Wilfrid Laurier University; Concern Foundation","keywords":"Chemistry; Deoxygenation; Epoxide; Catalysis; Steric effects; Bimetallic strip; Photochemistry; Solvent; Inorganic chemistry; Medicinal chemistry; Crystallography; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002017835,0.0002253945,0.0003519382,0.0001088397,0.00007495135,0.00002659055,0.0002400539,0.0001653608,0.00008271625],"category_scores_gemma":[0.0005966589,0.0002042225,0.00006562657,0.0005233325,0.0001822646,0.0001663912,0.0001513415,0.000184082,0.000002973018],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002446798,"about_ca_system_score_gemma":0.00007501904,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002928107,"about_ca_topic_score_gemma":0.0001035632,"domain_scores_codex":[0.9983039,0.0000117669,0.0008030526,0.0003282789,0.0003377178,0.0002153165],"domain_scores_gemma":[0.9987245,0.0001729593,0.0004151581,0.0003310222,0.0002931322,0.0000632401],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009255752,0.00004951127,0.0009616594,0.0006854961,0.00005127328,0.000002268837,0.0007242105,0.00009489084,0.9971544,0.0001105918,0.000001056238,0.00007211377],"study_design_scores_gemma":[0.0006482259,0.00001337654,0.01494486,0.0002034596,0.00005029139,0.00002275002,0.0001937889,0.007691982,0.9759527,0.00007541654,0.000005204463,0.0001978875],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9946659,0.00004635779,0.004837739,0.00003404803,0.00005036288,0.0001870899,0.00002536506,0.00006109897,0.00009206877],"genre_scores_gemma":[0.9994465,0.00004692167,0.00009816972,0.00001286287,0.00008489636,0.00002034677,0.0001977194,0.00004295377,0.00004963044],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02120161,"threshold_uncertainty_score":0.8327953,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008388578454061523,"score_gpt":0.2167188088422966,"score_spread":0.2083302303882351,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}