{"id":"W2899114954","doi":"10.1139/cjp-2018-0503","title":"Investigation on the mechanism of ESIPT of 2-hydroxy-1-naphthaldehyde-(4-pyridinecarboxylic)-hydrazone and detection of Al<sup>3+</sup> ion","year":2018,"lang":"en","type":"article","venue":"Canadian Journal of Physics","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Project of Shandong Province Higher Educational Science and Technology Program","keywords":"Intramolecular force; Excited state; Molecular orbital; Singlet state; Fluorescence; Photochemistry; Hydrazone; Hydrogen bond; Ion; Spectral line; Atomic physics; Molecular physics; Physics; Molecule; Chemistry; Stereochemistry; Optics","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001339454,0.0002679292,0.0001591799,0.0001040019,0.0001020823,0.00012874,0.0003259155,0.0003700533,0.0007073925],"category_scores_gemma":[0.0002018737,0.0001163683,0.00020201,0.00005920216,0.0002777499,0.0003091658,0.0001198873,0.0002332679,0.0001546471],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002662808,"about_ca_system_score_gemma":0.0001166265,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007136147,"about_ca_topic_score_gemma":0.0004677965,"domain_scores_codex":[0.9999286,0.00001385408,0.000002396986,0.00001424992,0.00002820299,0.00001266978],"domain_scores_gemma":[0.9999044,0.0000345925,0.00003166083,0.000006044813,0.00001667605,0.000006604121],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005590093,0.000006703792,0.0003319669,0.00005976808,0.000004854,0.0001121352,0.0000254869,0.0002519721,0.9972904,0.0003031022,0.0000230226,0.001534832],"study_design_scores_gemma":[0.000002913427,0.00007859275,0.001358585,0.000001530588,0.000004923917,0.0002286613,0.0000151752,0.004075306,0.9938506,0.00007292408,0.0003076934,0.000003081468],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.985941,0.001085058,0.01140472,0.000163687,0.0000108444,0.00002724757,0.00006367145,0.00008831437,0.001215371],"genre_scores_gemma":[0.9952219,0.0003832864,0.003578566,0.00002811572,0.000002999823,0.000009787719,0.00003112186,0.000003950412,0.0007403219],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007136147,"threshold_uncertainty_score":0.002366424,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.018222065644627,"score_gpt":0.2021099091731787,"score_spread":0.1838878435285517,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}