{"id":"W2899600493","doi":"10.1039/c8dt04409k","title":"Redox-state dependent activation of silanes and ammonia with reverse polarity (PC <sub>carbene</sub> P)Ni complexes: electrophilic <i>vs.</i> nucleophilic carbenes","year":2018,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"Calgary Laboratory Services; University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Carbene; Electrophile; Nucleophile; Chemistry; Cationic polymerization; Ligand (biochemistry); Alkyl; Medicinal chemistry; Silanes; Redox; Nucleophilic addition; Photochemistry; Polymer chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0001039276,0.0004157562,0.000481517,0.00008872118,0.0003758954,0.00005423924,0.0002885784,0.0002499319,0.0005304291],"category_scores_gemma":[0.00002084476,0.0004140359,0.0001144063,0.0003185505,0.0004911151,0.000269909,0.0000296714,0.0004761492,0.00001230174],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000185783,"about_ca_system_score_gemma":0.0001320911,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006284328,"about_ca_topic_score_gemma":0.0006706944,"domain_scores_codex":[0.9978474,0.00003363459,0.000538229,0.0006626333,0.0004306694,0.0004873783],"domain_scores_gemma":[0.9985143,0.00009013308,0.0002759068,0.0007149577,0.0001982889,0.0002064082],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003161138,0.0001796637,0.0006043045,0.0002725634,0.0001685262,0.000005278159,0.0005301505,0.00001342874,0.9958217,0.00002070785,0.00007345794,0.001994089],"study_design_scores_gemma":[0.001182386,0.0001642325,0.000758346,0.000122725,0.0001895458,0.000187411,0.0003007443,0.00008105479,0.9953762,0.0001344923,0.001080488,0.0004224116],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9961385,0.0001423683,0.001192069,0.0002433157,0.0001072614,0.0001588479,0.000340835,0.0001832012,0.001493673],"genre_scores_gemma":[0.9985718,0.0004350321,0.0001715919,0.0001115646,0.0002087152,0.0000202974,0.0000720111,0.00007917202,0.0003298873],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0024333,"threshold_uncertainty_score":0.9998311,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006387420078025029,"score_gpt":0.2059980968272682,"score_spread":0.1996106767492432,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}