{"id":"W2900381927","doi":"10.1039/c8dt04221g","title":"A comparative analysis of hydrosilative amide reduction catalyzed by first-row transition metal (Mn, Fe, Co, and Ni) <i>N</i>-phosphinoamidinate complexes","year":2018,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"Alberta Hospital Edmonton; University of Alberta; Dalhousie University","funders":"","keywords":"Transition metal; Catalysis; Amide; Chemistry; Nickel; Reduction (mathematics); Manganese; Medicinal chemistry; Stereochemistry; Crystallography; Organic chemistry; Mathematics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001586798,0.0002665376,0.0006493025,0.0005059082,0.0004702827,0.00003703805,0.0001412582,0.0001449148,0.001318134],"category_scores_gemma":[0.00001221857,0.0002805546,0.0003092454,0.002145505,0.0005088476,0.0002936613,0.000005083602,0.0001968168,0.00001169968],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001027905,"about_ca_system_score_gemma":0.00003032214,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001289834,"about_ca_topic_score_gemma":0.0007363037,"domain_scores_codex":[0.9983385,0.00005186523,0.0005273236,0.0004791113,0.0003590149,0.0002442041],"domain_scores_gemma":[0.9989066,0.0001398627,0.0002746235,0.0003033995,0.0002270224,0.0001484676],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000441835,0.001127378,0.0003507365,0.0001765223,0.01059538,0.000002549473,0.02439319,0.002216712,0.9558153,0.0002696238,0.0009565788,0.003654243],"study_design_scores_gemma":[0.00076702,0.00005649082,0.0002711371,0.00001573102,0.003563235,0.000007816418,0.002381401,0.02397552,0.9663756,0.00005131131,0.002235519,0.0002991755],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9033384,0.0003751118,0.08734711,0.0002847762,0.0000730891,0.0001819123,0.005059015,0.0001456276,0.003195004],"genre_scores_gemma":[0.9963539,0.000133536,0.0002484203,0.00002636109,0.00003087998,0.00004575167,0.002709771,0.00001687898,0.0004345484],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0930155,"threshold_uncertainty_score":0.9999647,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01591930739862852,"score_gpt":0.2665704937052433,"score_spread":0.2506511863066148,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}