{"id":"W2900827821","doi":"10.1039/c8cc08158a","title":"Expanding the chemistry of ring-fused 1,4-diphosphinines by stable mono anion formation","year":2018,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"Lethbridge College; University of Lethbridge","funders":"Natural Sciences and Engineering Research Council of Canada; Rheinische Friedrich-Wilhelms-Universität Bonn; Hungarian Scientific Research Fund; Budapesti Műszaki és Gazdaságtudományi Egyetem; European Cooperation in Science and Technology; Alexander von Humboldt-Stiftung","keywords":"Ring (chemistry); Ion; Chemistry; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001791428,0.0001693819,0.0002018375,0.00001504001,0.0003541154,0.00005036521,0.001614127,0.000143819,0.0006327081],"category_scores_gemma":[0.0002832287,0.0001458896,0.00008504643,0.0002451458,0.0005347832,0.0001882651,0.0005811136,0.0002798092,0.0000341739],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001277562,"about_ca_system_score_gemma":0.00003646528,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005985126,"about_ca_topic_score_gemma":0.000003706288,"domain_scores_codex":[0.9989079,0.00002212041,0.0004341655,0.0001859993,0.0002098023,0.000239985],"domain_scores_gemma":[0.9968476,0.0004596414,0.0002643271,0.002186219,0.0001714784,0.00007073655],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001444766,0.0001110495,0.0002364796,0.00004509537,0.00002494944,4.022825e-8,0.0004549343,3.193285e-7,0.9950421,0.00009055599,0.003201135,0.0007788922],"study_design_scores_gemma":[0.0002276037,0.000004733845,0.00001514939,0.00006944936,0.00003274664,0.000003740067,0.0004017841,0.0009052531,0.9799891,0.0003974565,0.01779874,0.0001542647],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9532738,0.001062296,0.0002853206,0.001217747,0.00002528121,0.00008820998,0.00006487198,0.0001627899,0.04381973],"genre_scores_gemma":[0.997389,0.0001906717,0.001525654,0.0000389679,0.0000692586,0.00005525753,0.0001445094,0.00003138715,0.0005552724],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04411526,"threshold_uncertainty_score":0.692771,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02229777326011965,"score_gpt":0.2583722769037162,"score_spread":0.2360745036435965,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}