{"id":"W2900999937","doi":"10.1039/c8ob02330a","title":"Protic additives or impurities promote imine reduction with pinacolborane","year":2018,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada; Killam Trusts; Department of Agriculture, Nova Scotia","keywords":"Chemistry; Imine; Reduction (mathematics); Impurity; Combinatorial chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001814439,0.0004682542,0.0002281318,0.0001902378,0.0001409938,0.0002516662,0.0003334933,0.0002439873,0.001614824],"category_scores_gemma":[0.0003064084,0.0001650939,0.0001522487,0.000127515,0.0002006369,0.000410288,0.0002512373,0.0003995918,0.0005852054],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001180382,"about_ca_system_score_gemma":0.0001043699,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004555265,"about_ca_topic_score_gemma":0.001459726,"domain_scores_codex":[0.999759,0.00006124951,0.00001837927,0.00005935793,0.00005415307,0.00004785842],"domain_scores_gemma":[0.9998846,0.00004587218,0.00002852615,0.00001339926,0.00001529263,0.00001237141],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006741626,0.00001828344,0.00009672482,0.0001060289,0.000008978826,0.00009385106,0.00005120797,0.0001013264,0.9966776,0.0001672848,0.00004916321,0.002562069],"study_design_scores_gemma":[0.000001891453,0.00008955415,0.0002073021,0.000003975053,0.0000055169,0.00005532451,0.000009280414,0.000185999,0.9982795,0.00001722202,0.001142251,0.000002377129],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9723512,0.00313311,0.01004969,0.0001557517,0.00006020032,0.00008284739,0.0001950751,0.0002282706,0.0137438],"genre_scores_gemma":[0.9916367,0.001230383,0.004360665,0.00004394615,0.00001393165,0.0000168581,0.0001378451,0.00004151399,0.00251815],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001614824,"threshold_uncertainty_score":0.005402088,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006298294002185912,"score_gpt":0.2206370181920228,"score_spread":0.2143387241898369,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}