{"id":"W2901357619","doi":"10.1002/anie.201812592","title":"Facile Cleavage of the P=P Double Bond in Vinyl‐Substituted Diphosphenes","year":2018,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":54,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Cleavage (geology); Bond cleavage; Double bond; Chemistry; Polymer chemistry; Materials science; Organic chemistry; Composite material; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001171172,0.0002652022,0.00008561533,0.0001415062,0.0001297476,0.000268427,0.0001871227,0.0002129054,0.002124911],"category_scores_gemma":[0.000189283,0.000158037,0.0001114427,0.0001007172,0.0001528749,0.0003451203,0.0003297733,0.0004270227,0.0005545964],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002309396,"about_ca_system_score_gemma":0.0002033843,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002284278,"about_ca_topic_score_gemma":0.000563839,"domain_scores_codex":[0.9998925,0.00001269759,0.000008272162,0.00002589024,0.0000263175,0.00003436051],"domain_scores_gemma":[0.9999413,0.00001574528,0.00001258251,0.00001018748,0.000006399364,0.0000136905],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004842,0.00001774329,0.0001210868,0.00009297088,0.000006116751,0.0001941566,0.00006196019,0.000329095,0.9924753,0.001830856,0.0001658725,0.004656355],"study_design_scores_gemma":[0.00001541429,0.0001387062,0.0005700075,0.000006552705,0.000003726434,0.000198133,0.00001908195,0.0005057906,0.994122,0.0001868125,0.004228154,0.000005746979],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9778756,0.0008197393,0.005918751,0.0001086393,0.0000415202,0.00004381741,0.0003396657,0.00009107363,0.01476124],"genre_scores_gemma":[0.9956238,0.0003412294,0.001979892,0.00002243419,0.000003395976,0.00001365434,0.0001240434,0.00001258809,0.00187896],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002124911,"threshold_uncertainty_score":0.00710851,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0168937809255238,"score_gpt":0.2397055426371475,"score_spread":0.2228117617116237,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}