{"id":"W2901803776","doi":"10.1071/ch18380","title":"Fluctuations and Mixing State of an Aqueous Solution of the Ionic Liquid Tetrabutylphosphonium Trifluoroacetate around the Critical Point","year":2018,"lang":"en","type":"article","venue":"Australian Journal of Chemistry","topic":"Ionic liquids properties and applications","field":"Chemical Engineering","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Japan Society for the Promotion of Science; University of British Columbia","keywords":"Ionic liquid; Chemistry; Critical point (mathematics); Aqueous solution; Mesoscopic physics; Phase transition; Mixing (physics); Thermodynamics; Phase (matter); Isothermal process; Physical chemistry; Condensed matter physics; Physics; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003036273,0.0001109921,0.0001826707,0.00001424035,0.0001299103,0.00002221051,0.000317571,0.00006472555,0.00007100712],"category_scores_gemma":[0.0001932928,0.00006788492,0.0001089325,0.0001323329,0.0004898908,0.0001413508,0.00004894366,0.0003146918,9.365726e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004694123,"about_ca_system_score_gemma":0.0001011343,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002247776,"about_ca_topic_score_gemma":0.000001437803,"domain_scores_codex":[0.9989072,0.0000240607,0.0005509446,0.0001043746,0.0002198815,0.0001935553],"domain_scores_gemma":[0.9989901,0.00008269498,0.0002603408,0.0002745963,0.0003011976,0.00009113501],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007547477,0.00005157684,0.00000623153,0.00006925349,0.0000428012,9.538119e-7,0.0005083823,0.0005582881,0.9978791,0.00008950701,0.0001385399,0.0005798975],"study_design_scores_gemma":[0.0002750369,0.0001320241,0.00008939275,0.0001281626,0.00006905617,0.0001634327,0.0003349936,0.001752112,0.9961,0.0006446549,0.0002307227,0.00008042515],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.995314,0.0001930117,0.001015167,0.003153047,0.00009083321,0.00006511588,0.0000139199,0.000007348572,0.0001475369],"genre_scores_gemma":[0.9987078,0.00002742985,0.0006120866,0.0000244506,0.0002029144,0.000002970642,0.000001276529,0.00001302019,0.0004080963],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003393735,"threshold_uncertainty_score":0.2768267,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01542712489527596,"score_gpt":0.2564752946081498,"score_spread":0.2410481697128739,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}