{"id":"W2902477728","doi":"10.1002/ejoc.201801639","title":"Iron‐ or Zinc‐Mediated Synthetic Approach to Enantiopure Dihydroquinoxalinones","year":2018,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada; China Scholarship Council; Centre in Green Chemistry and Catalysis","keywords":"Enantiopure drug; Chemistry; Zinc; Enantiomer; Enantiomeric excess; Amino acid; Organic chemistry; Metal; Combinatorial chemistry; Enantioselective synthesis; Catalysis; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001594621,0.0003856551,0.0002794645,0.0001887265,0.0001690219,0.0001898807,0.0004598134,0.0002734306,0.001404876],"category_scores_gemma":[0.000131248,0.0001312356,0.0002140071,0.0001340488,0.0001957984,0.0002321601,0.0003007519,0.0003983832,0.0006858635],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002625075,"about_ca_system_score_gemma":0.0002398521,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004116277,"about_ca_topic_score_gemma":0.000932203,"domain_scores_codex":[0.9998932,0.00001673362,0.00001133847,0.00002494151,0.00002207536,0.00003176021],"domain_scores_gemma":[0.9999564,0.000006082687,0.000009297724,0.000007467413,0.00000951198,0.00001129062],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009292804,0.00005196075,0.0001451388,0.0002208128,0.00001297018,0.00077637,0.00007574569,0.0004556257,0.9845431,0.002377025,0.0003663042,0.01088185],"study_design_scores_gemma":[0.00004562276,0.0002573193,0.0004767608,0.00001410249,0.00001624971,0.0006799701,0.00002686937,0.0007282159,0.9804284,0.000383437,0.01692116,0.00002194786],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9064015,0.007676402,0.04715517,0.0005278662,0.0003504325,0.0003358619,0.001096082,0.0004546912,0.03600203],"genre_scores_gemma":[0.9757779,0.003316335,0.0149116,0.00009676634,0.00003379847,0.00005256251,0.000297461,0.00004520752,0.005468446],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001404876,"threshold_uncertainty_score":0.004699826,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008798259780602944,"score_gpt":0.2119573190383042,"score_spread":0.2031590592577012,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}