{"id":"W2902560500","doi":"10.1021/acs.organomet.8b00745","title":"High-Yield Synthesis of a Long-Sought, Labile Ru-NHC Complex and Its Application to the Concise Synthesis of Second-Generation Olefin Metathesis Catalysts","year":2018,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Synthon; Chemistry; Yield (engineering); Catalysis; Olefin fiber; Olefin metathesis; Metathesis; Ruthenium; Medicinal chemistry; Decomposition; Stoichiometry; Combinatorial chemistry; Salt metathesis reaction; Organic chemistry; Polymerization","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0008536821,0.0003567146,0.0007583845,0.00009800542,0.0001498707,0.00003596849,0.0006575324,0.0002347698,0.006006129],"category_scores_gemma":[0.002920431,0.0003004096,0.0001469325,0.0006088993,0.0002763507,0.00009478324,0.0002374431,0.0001381614,0.00007919723],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009030541,"about_ca_system_score_gemma":0.00009868727,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007674678,"about_ca_topic_score_gemma":0.0001926737,"domain_scores_codex":[0.9977156,0.0001071703,0.0008001201,0.0006187794,0.0004379768,0.0003203857],"domain_scores_gemma":[0.9961476,0.001594747,0.0005343393,0.00120804,0.0003479775,0.0001672598],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003193212,0.0001287788,0.0001399512,0.0003143554,0.0002216221,9.312811e-7,0.0004012684,0.000004665298,0.979257,0.0002060036,0.0002431346,0.0190504],"study_design_scores_gemma":[0.0001424544,0.00002419113,0.0008613497,0.00006219784,0.0004611672,0.00002152922,0.0002013856,0.0002941454,0.9957317,0.00004291403,0.001860051,0.0002968929],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9940232,0.000264857,0.001454163,0.000723728,0.00006882758,0.0003173736,0.0004405236,0.0000637858,0.002643525],"genre_scores_gemma":[0.9931954,0.00005230579,0.005465867,0.00006820364,0.0003274677,0.0001679196,0.0000330843,0.00007760533,0.0006121816],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0187535,"threshold_uncertainty_score":0.9999448,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02992572037223568,"score_gpt":0.2636856021442915,"score_spread":0.2337598817720558,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}