{"id":"W2902698353","doi":"10.1039/c8sc04210a","title":"The opposite and amplifying effect of B ← N coordination on photophysical properties of regioisomers with an unsymmetrical backbone","year":2018,"lang":"en","type":"article","venue":"Chemical Science","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":28,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada; National Natural Science Foundation of China","keywords":"Structural isomer; Chemistry; Stereochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001442509,0.0002389635,0.00007661356,0.0001226878,0.0001172202,0.0001722331,0.0001821563,0.0001801953,0.002815059],"category_scores_gemma":[0.0002203238,0.0001184454,0.0001161027,0.0001006141,0.0002091751,0.0002177897,0.0001311728,0.0002723664,0.0004842166],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009114767,"about_ca_system_score_gemma":0.0001042235,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002376131,"about_ca_topic_score_gemma":0.0004303862,"domain_scores_codex":[0.9998963,0.00002300368,0.000005428267,0.00003080847,0.00002025939,0.00002409492],"domain_scores_gemma":[0.999893,0.00002320075,0.00002850781,0.00001814876,0.0000152477,0.00002194438],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001138472,0.00001145742,0.0002286906,0.00002070637,0.000004348108,0.00003405734,0.00003096435,0.00005615122,0.9974239,0.0002345298,0.00003907446,0.001802408],"study_design_scores_gemma":[0.000009301922,0.0002910282,0.003010514,0.00000267692,0.000008919078,0.0001931728,0.00003993515,0.0004276389,0.9946561,0.00007679423,0.001276914,0.000007008874],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9942064,0.0001797477,0.001570724,0.00002500429,0.000007290112,0.0000103916,0.00009075837,0.00003925371,0.003870332],"genre_scores_gemma":[0.9974147,0.00009305671,0.001218397,0.00002281932,0.000002246525,0.00001104041,0.00009148783,0.00001696681,0.00112923],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002815059,"threshold_uncertainty_score":0.009417355,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01332406178664023,"score_gpt":0.2469933688070619,"score_spread":0.2336693070204217,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}