{"id":"W2904010668","doi":"10.1002/poc.3920","title":"Photochemical generation of 9‐Fluorenyl radicals","year":2018,"lang":"en","type":"article","venue":"Journal of Physical Organic Chemistry","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University; McMaster University","funders":"","keywords":"Chemistry; Antiaromaticity; Radical; Photochemistry; Flash photolysis; Density functional theory; Polar; Irradiation; Photochromism; Computational chemistry; Molecule; Organic chemistry; Aromaticity; Reaction rate constant; Kinetics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001517657,0.0002137999,0.0001311993,0.0001252615,0.000179641,0.0001132131,0.0001599745,0.0003202427,0.003272234],"category_scores_gemma":[0.0001229051,0.00007487721,0.0001700202,0.0001099676,0.0001414742,0.0001911021,0.0001402405,0.0002816672,0.0002470074],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000186129,"about_ca_system_score_gemma":0.0001266089,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004719327,"about_ca_topic_score_gemma":0.0004850611,"domain_scores_codex":[0.9999171,0.0000114688,0.000002304932,0.00001821549,0.00001381237,0.00003706908],"domain_scores_gemma":[0.9999226,0.00002302233,0.00002105457,0.000007031104,0.00001469259,0.00001153922],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002278911,0.00001830518,0.0001842919,0.00007248067,0.000006969166,0.00006870001,0.0000343766,0.0002069587,0.9965127,0.0002790506,0.00007325216,0.002315048],"study_design_scores_gemma":[0.000009683851,0.0002308705,0.0006413375,0.000004312212,0.00000460632,0.00005782561,0.00001587494,0.000222865,0.998121,0.0000375381,0.0006510595,0.000003041408],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9953929,0.0007195056,0.001670846,0.0000380103,0.00002279784,0.0000165463,0.0001860036,0.00002825984,0.001925173],"genre_scores_gemma":[0.9984251,0.0001813466,0.0004318357,0.00001287761,0.000002218066,0.000004454962,0.00006893762,0.000002688063,0.0008704672],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003272234,"threshold_uncertainty_score":0.01094669,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.07783670832628693,"score_gpt":0.4125367418458243,"score_spread":0.3347000335195374,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}