{"id":"W2905017691","doi":"10.1039/c8cc08942f","title":"Hydrogen bonding promoted simple and clean photo-induced reduction of C–X bond with isopropanol","year":2018,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":47,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Natural Sciences and Engineering Research Council of Canada; Recruitment Program of Global Experts; Lanzhou University; Science and Technology Department of Gansu Province; Fonds Québécois de la Recherche sur la Nature et les Technologies; Canada Research Chairs; Canada Foundation for Innovation","keywords":"Simple (philosophy); Hydrogen bond; Reduction (mathematics); Chemistry; Bond; Photochemistry; Materials science; Molecule; Organic chemistry; Business; Mathematics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007861049,0.0003442965,0.0001728123,0.00007932043,0.00009753155,0.0001199724,0.0004046487,0.0002383405,0.001479608],"category_scores_gemma":[0.00007643383,0.0001036205,0.0001936241,0.00006972919,0.0001375615,0.0002701387,0.0002924532,0.0006203608,0.0004257912],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001114465,"about_ca_system_score_gemma":0.0001141185,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002863256,"about_ca_topic_score_gemma":0.0005927695,"domain_scores_codex":[0.9999069,0.000006434036,0.000004681159,0.0000242754,0.00003359037,0.00002408968],"domain_scores_gemma":[0.9999634,0.000006074058,0.00001248946,0.000007846357,0.000005636066,0.000004586457],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000278082,0.00001732055,0.00005894011,0.0001265432,0.000008603781,0.00009136662,0.00003019706,0.00009542705,0.9958187,0.0003050711,0.0001858866,0.003234249],"study_design_scores_gemma":[0.000004811818,0.00007519036,0.0003023907,0.000002020326,0.000005409943,0.00007543729,0.000008042578,0.0002820008,0.997451,0.00002998065,0.001760123,0.000003719739],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.967689,0.00228851,0.0194062,0.0002236919,0.0001382311,0.00009510848,0.0003834568,0.0003481293,0.009427642],"genre_scores_gemma":[0.9882003,0.0007940589,0.006522815,0.00005406169,0.00001545189,0.00003511232,0.0001809003,0.00004692444,0.004150388],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001479608,"threshold_uncertainty_score":0.004949749,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03160775511658429,"score_gpt":0.2880774873994835,"score_spread":0.2564697322828992,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}