{"id":"W2905532070","doi":"10.1142/s1088424618501110","title":"Differential quenching of the angular momentum of the B and Q bands of a porphyrin as a result of extended ring π-conjugation","year":2018,"lang":"en","type":"article","venue":"Journal of Porphyrins and Phthalocyanines","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada; Fundacja na rzecz Nauki Polskiej; National Science Foundation","keywords":"Chemistry; Magnetic circular dichroism; Angular momentum; Porphyrin; Excited state; Crystallography; Photochemistry; Molecular physics; Spectral line; Atomic physics; Physics; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001033369,0.0001658195,0.0001072407,0.00007737082,0.00009834039,0.0001471245,0.0001451778,0.0001860167,0.0007467232],"category_scores_gemma":[0.000127521,0.00008139054,0.00007741066,0.000085261,0.0002803718,0.0001944744,0.0001693775,0.0003189943,0.00009471318],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001514115,"about_ca_system_score_gemma":0.0000795715,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002102115,"about_ca_topic_score_gemma":0.000163745,"domain_scores_codex":[0.9999319,0.000009752357,0.000002474484,0.00001992108,0.00001913663,0.00001669636],"domain_scores_gemma":[0.9999017,0.00002758575,0.00002979769,0.00001117372,0.00001019366,0.00001954072],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003663303,0.000004445456,0.00004939113,0.000008080207,0.000001117648,0.00002317301,0.00001210691,0.00003319957,0.9993492,0.00005071085,0.000006279186,0.0004255987],"study_design_scores_gemma":[0.000007003302,0.00009819602,0.001214385,0.000001549405,0.000002822698,0.00007357327,0.000008148422,0.0005530792,0.9977542,0.00003253582,0.0002521482,0.000002351573],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9978985,0.0001467645,0.001312994,0.000022483,0.000002966405,0.000003314497,0.00001589669,0.00002572033,0.0005713693],"genre_scores_gemma":[0.9988042,0.00006326361,0.0006594345,0.00001058931,0.000001486,0.000003035871,0.00001996534,0.000006314026,0.0004316959],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007467232,"threshold_uncertainty_score":0.002498031,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007790403396907399,"score_gpt":0.2364458162348195,"score_spread":0.2286554128379121,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}