{"id":"W2905534301","doi":"10.1021/acs.jnatprod.8b00787","title":"Fusaristatin C, a Cyclic Lipodepsipeptide from <i>Pithomyces</i> sp. RKDO 1698","year":2018,"lang":"en","type":"article","venue":"Journal of Natural Products","topic":"Microbial Natural Products and Biosynthesis","field":"Medicine","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"Nautilus Biosciences (Canada); University of Prince Edward Island","funders":"Natural Sciences and Engineering Research Council of Canada; Atlantic Canada Opportunities Agency; Canada Research Chairs; Canada Foundation for Innovation; Innovation PEI","keywords":"Absolute configuration; Stereochemistry; Residue (chemistry); Mass spectrometry; Serine; Chemistry; Nuclear magnetic resonance spectroscopy; Cytotoxicity; Organic chemistry; Chromatography; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006428564,0.0003245015,0.0007303346,0.0002462119,0.0001502132,0.00007957984,0.0003426031,0.0001673702,0.0002861719],"category_scores_gemma":[0.002164049,0.0002066375,0.0002375561,0.0006198325,0.0002499358,0.0003967127,0.00008784539,0.001055156,0.0001629835],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001190711,"about_ca_system_score_gemma":0.0002670077,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008710483,"about_ca_topic_score_gemma":0.0000178167,"domain_scores_codex":[0.99748,0.0001087391,0.0008673912,0.0004690015,0.0006358143,0.0004390414],"domain_scores_gemma":[0.9968812,0.0001154123,0.0007519099,0.0005027468,0.0015272,0.0002215215],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001217761,0.0001738469,0.0005442419,0.00006487744,0.0001979273,0.0001683413,0.0002312189,1.615082e-7,0.8405142,0.00001664722,0.13699,0.01988078],"study_design_scores_gemma":[0.001471252,0.0008072761,0.01287177,0.0003910472,0.0003121977,0.00106361,0.00008048558,0.0000111886,0.8034557,0.0003351076,0.1789071,0.0002933718],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9631355,0.006876765,0.000007291044,0.02517454,0.003670793,0.0003320049,0.00002464344,0.00004419093,0.0007342956],"genre_scores_gemma":[0.9673046,0.0002830831,0.01509693,0.002307343,0.01252121,2.360625e-7,0.00001851215,0.00004057106,0.002427471],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04191709,"threshold_uncertainty_score":0.8426431,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01328197793211173,"score_gpt":0.2574234169484535,"score_spread":0.2441414390163418,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}