{"id":"W2907994158","doi":"10.1021/acsami.8b14744","title":"Heteroleptic Ir(III)N<sub>6</sub> Complexes with Long-Lived Triplet Excited States and in Vitro Photobiological Activities","year":2019,"lang":"en","type":"article","venue":"ACS Applied Materials & Interfaces","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":60,"is_retracted":false,"has_abstract":true,"ca_institutions":"Acadia University","funders":"Division of Materials Research; National Cancer Institute; Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation; Nova Scotia Research Innovation Trust; Canadian Institutes of Health Research; Acadia University","keywords":"Excited state; Diimine; Substituent; Photochemistry; Iridium; Materials science; Ligand (biochemistry); Singlet state; Phosphorescence; Phenanthroline; Crystallography; Fluorescence; Chemistry; Stereochemistry; Atomic physics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002977319,0.0003861592,0.0006677746,0.0001749388,0.00004659631,0.000279162,0.000298341,0.0001678914,0.0001489699],"category_scores_gemma":[0.00001097481,0.0003032863,0.00001273887,0.0001482744,0.0001769191,0.0001709023,0.0002013429,0.0002407563,0.0001064829],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009787083,"about_ca_system_score_gemma":0.00001432276,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000421537,"about_ca_topic_score_gemma":0.00003055289,"domain_scores_codex":[0.9982132,0.00007760517,0.0004236668,0.0004624226,0.0002185667,0.0006045367],"domain_scores_gemma":[0.9992682,0.0002448184,0.00008010814,0.0003109302,0.0000235316,0.00007242186],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0009388336,0.00003861483,0.0002637199,0.0002542493,0.00009507098,0.000009131865,0.0006734252,0.0001657766,0.9973688,0.000007989423,0.00005001136,0.0001344178],"study_design_scores_gemma":[0.001331347,0.0001442162,0.001180951,0.00008899593,0.00001369231,0.00001356093,0.0005887018,0.0001031611,0.9961209,0.00003216357,0.00001345132,0.0003688695],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9983268,0.0001420066,0.0000249073,0.00002438183,0.0001584279,0.0007562686,0.00007441069,0.0003046284,0.00018816],"genre_scores_gemma":[0.9993137,0.0002094933,0.00008668147,0.00003932237,0.00005011795,0.0001280839,0.00007011001,0.00007699907,0.00002553527],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00124787,"threshold_uncertainty_score":0.9999419,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008723265600762116,"score_gpt":0.2127107004703189,"score_spread":0.2039874348695568,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}