{"id":"W2908906574","doi":"10.1080/10610278.2018.1564829","title":"Chiral phosphine ligand libraries based on the Bull–James three-component supramolecular assembly","year":2019,"lang":"en","type":"article","venue":"Supramolecular chemistry","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"American Chemical Society Petroleum Research Fund; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Canada Foundation for Innovation","keywords":"Chemistry; Allylic rearrangement; Phosphine; Ligand (biochemistry); Trimethylsilyl; Tetrahydrofuran; Stereocenter; Stereochemistry; Denticity; Nuclear magnetic resonance spectroscopy; Medicinal chemistry; Organic chemistry; Enantioselective synthesis; Catalysis; Crystal structure","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002308421,0.0006059108,0.000482966,0.0006637713,0.000301786,0.0007890155,0.0005260169,0.0003462475,0.001653113],"category_scores_gemma":[0.0002491016,0.0003273682,0.0002581604,0.0004403512,0.0002253779,0.0004469785,0.0006767139,0.0006522596,0.00129561],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005065703,"about_ca_system_score_gemma":0.0002349823,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003058002,"about_ca_topic_score_gemma":0.0007507363,"domain_scores_codex":[0.9997903,0.00003800092,0.0000150584,0.00004516328,0.00006769758,0.00004388138],"domain_scores_gemma":[0.9999118,0.00001322095,0.00001576276,0.00001420544,0.00001472472,0.00003024666],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009072944,0.00007122902,0.000101026,0.00007186645,0.00001733442,0.0000919313,0.00004097444,0.001207403,0.9794413,0.001615908,0.0003954236,0.01685496],"study_design_scores_gemma":[0.00005165536,0.0003116857,0.0003897147,0.000007992449,0.00002802334,0.0001868591,0.00001398347,0.007145202,0.9794784,0.0003835403,0.0119756,0.00002728356],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8264892,0.003560174,0.1359838,0.0003968191,0.0001679792,0.0008141874,0.001067771,0.004052834,0.02746733],"genre_scores_gemma":[0.942296,0.001400718,0.04382277,0.0002469099,0.00003095566,0.0003808995,0.001024949,0.0002189065,0.01057792],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001653113,"threshold_uncertainty_score":0.005530179,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005106743434213136,"score_gpt":0.1878318895324128,"score_spread":0.1827251460981996,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}