{"id":"W2909429949","doi":"10.1021/acs.chemmater.8b03074","title":"Silicon Nanoparticles: Are They Crystalline from the Core to the Surface?","year":2019,"lang":"en","type":"article","venue":"Chemistry of Materials","topic":"Silicon Nanostructures and Photoluminescence","field":"Materials Science","cited_by":75,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; University of Alberta","keywords":"X-ray photoelectron spectroscopy; Silicon; Materials science; Nanoparticle; Photoluminescence; Fourier transform infrared spectroscopy; Nanotechnology; Photovoltaics; Spectroscopy; Quantum dot; Crystalline silicon; Chemical engineering; Nanostructure; Optoelectronics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003994432,0.0001788247,0.0003098273,0.000003323366,0.00009047423,0.0001093999,0.0008634125,0.00008401336,0.005872337],"category_scores_gemma":[0.000155094,0.00009615466,0.00005248461,0.00006963333,0.0001053955,0.00005120116,0.0001947132,0.00005429849,0.000263263],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001629326,"about_ca_system_score_gemma":0.00003654445,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000505036,"about_ca_topic_score_gemma":0.00002461115,"domain_scores_codex":[0.9987173,0.00005462892,0.0003745026,0.0003228698,0.0002708505,0.0002598536],"domain_scores_gemma":[0.9984972,0.0002286229,0.0002577,0.0008627971,0.00008596248,0.00006774006],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001010254,0.00001551275,0.001492459,0.00005308284,0.00000675651,0.000001165249,0.0004073669,0.0001388157,0.996105,0.00001033536,0.001659292,0.000009246312],"study_design_scores_gemma":[0.0002167624,0.0000168422,0.004982238,0.0000841793,0.00001373632,0.000004779144,0.0004079295,0.000007232062,0.9920849,0.0001668183,0.001881883,0.0001326559],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.997305,0.0001478568,4.531591e-7,0.0008420694,0.0005443293,0.0003538648,0.0006827646,0.00003438058,0.00008925045],"genre_scores_gemma":[0.9989228,0.000008801856,0.00003767377,0.0003792725,0.0002284925,0.00001152675,0.00002181772,0.00001696448,0.0003726626],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005609074,"threshold_uncertainty_score":0.9950364,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01479880674876766,"score_gpt":0.2307455348761565,"score_spread":0.2159467281273888,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}