{"id":"W2909689788","doi":"10.1039/c9tc00040b","title":"Exploiting synergy between ligand design and counterion interactions to boost room temperature phosphorescence from Cu(<scp>i</scp>) compounds","year":2019,"lang":"en","type":"article","venue":"Journal of Materials Chemistry C","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":38,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Winnipeg; University of Manitoba; Children's Hospital Research Institute of Manitoba","funders":"Natural Sciences and Engineering Research Council of Canada; Association of Commonwealth Universities; University of Manitoba","keywords":"Counterion; Phosphorescence; Ligand (biochemistry); Ion; Materials science; Photochemistry; Combinatorial chemistry; Chemistry; Organic chemistry; Fluorescence; Receptor; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001140868,0.0003746041,0.000164736,0.0001472835,0.0001761554,0.0004571217,0.0002756142,0.000305376,0.001957116],"category_scores_gemma":[0.000200119,0.0001319273,0.0001138536,0.0001482679,0.0001854228,0.0003189511,0.0002578921,0.0003505669,0.0004958546],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003001487,"about_ca_system_score_gemma":0.0002349758,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004375362,"about_ca_topic_score_gemma":0.001254596,"domain_scores_codex":[0.9999201,0.00001018784,0.00000474008,0.00001943627,0.0000146522,0.0000308519],"domain_scores_gemma":[0.9999501,0.0000110273,0.00001429866,0.000004488329,0.000009017513,0.0000110732],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002710281,0.00004539556,0.0002174263,0.0002069661,0.00001282893,0.0001109814,0.00004169869,0.0008729125,0.9804967,0.001467774,0.001305065,0.01495119],"study_design_scores_gemma":[0.00002710243,0.0001691585,0.0001932598,0.000009253247,0.00001214914,0.00008983171,0.00002188587,0.002377507,0.9926668,0.0001205418,0.004301564,0.00001094055],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.973229,0.001771388,0.01121429,0.000638067,0.0001235361,0.00004677612,0.0001790796,0.0006482038,0.01214974],"genre_scores_gemma":[0.9893244,0.0006308301,0.006724732,0.0001536294,0.00001568717,0.00003890841,0.00009157933,0.0000680236,0.002952298],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001957116,"threshold_uncertainty_score":0.006547213,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01285865974674241,"score_gpt":0.2368934734692529,"score_spread":0.2240348137225104,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}