{"id":"W2911393713","doi":"10.1016/j.tetlet.2019.02.025","title":"Isolation, chemical characterization and hydrolysis of the trichothecene 7α-hydroxy, 15-deacetylcalonectrin (3ANX) from Fusarium graminearum DAOMC 242077","year":2019,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Mycotoxins in Agriculture and Food","field":"Agricultural and Biological Sciences","cited_by":20,"is_retracted":false,"has_abstract":false,"ca_institutions":"Carleton University","funders":"Natural Sciences and Engineering Research Council of Canada; Ontario Ministry of Agriculture, Food and Rural Affairs; Carleton University","keywords":"Trichothecene; Mycotoxin; Chemistry; Fusarium; Hydrolysis; Food science; Organic chemistry; Botany; Biology","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009817455,0.0005090628,0.0001942639,0.0002990764,0.000221022,0.0001831431,0.0001374969,0.0001727901,0.001119699],"category_scores_gemma":[0.0001493339,0.0001043836,0.000276289,0.0003245754,0.0001751438,0.0001425313,0.0001538428,0.0002536495,0.0005346248],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002579518,"about_ca_system_score_gemma":0.0003350408,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.005244622,"about_ca_topic_score_gemma":0.003911889,"domain_scores_codex":[0.9999013,0.000009431616,0.000006775596,0.00001732471,0.00003505026,0.00003013874],"domain_scores_gemma":[0.9999188,0.0000126236,0.00001409506,0.000007938387,0.00002764414,0.00001888548],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005360971,0.000009397995,0.0001275651,0.000009993643,0.000002201241,0.00006517371,0.00001069539,0.00004419835,0.9982811,0.00001639324,0.00001375171,0.001366055],"study_design_scores_gemma":[0.000006727619,0.0001262117,0.007562447,0.000002942781,0.00000894863,0.0001484192,0.00003360879,0.000222232,0.9898713,0.00001484875,0.001996992,0.000005288259],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9905483,0.001117283,0.004391596,0.00008526543,0.00002604926,0.00007044364,0.001129323,0.00003139745,0.002600351],"genre_scores_gemma":[0.9835481,0.0008821786,0.003984325,0.00004652726,0.00001059906,0.00003792548,0.004515051,0.00002661059,0.006948746],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005244622,"threshold_uncertainty_score":0.01042819,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004542498367503135,"score_gpt":0.16151541974385,"score_spread":0.1569729213763469,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}