{"id":"W2911450404","doi":"10.1002/anie.201813431","title":"Size‐Control by Anion Templating in Mechanochemical Synthesis of Hemicucurbiturils in the Solid State","year":2019,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":48,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Haridus- ja Teadusministeerium","keywords":"Solid-state; Ion; Materials science; Chemical engineering; Crystallography; Chemistry; Engineering; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001535461,0.0002265873,0.0001102288,0.00009735361,0.0001009973,0.0002308498,0.0001638369,0.0001531102,0.0006523056],"category_scores_gemma":[0.0001308571,0.000108274,0.0001028746,0.00009006611,0.0002377495,0.0002814276,0.000205662,0.0003073812,0.0002239028],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001692153,"about_ca_system_score_gemma":0.0001156695,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001812262,"about_ca_topic_score_gemma":0.0005505851,"domain_scores_codex":[0.9999052,0.00001570124,0.000008405662,0.00002854347,0.0000245153,0.00001745024],"domain_scores_gemma":[0.9999208,0.00001764302,0.00003561507,0.000008434083,0.000007114033,0.00001029613],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001793965,0.000007411902,0.00004556815,0.000024405,0.000001286155,0.00002421457,0.00002195335,0.00009956474,0.9981804,0.0003303815,0.00001724157,0.001229652],"study_design_scores_gemma":[0.000003238353,0.00005400128,0.0002273547,0.00000179861,0.00000162488,0.00003113149,0.000005498976,0.0005304824,0.9979346,0.00003401718,0.001172823,0.000003430692],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9892842,0.0009166412,0.006907277,0.00007502213,0.00003104755,0.00002183118,0.00006631536,0.000105024,0.002592742],"genre_scores_gemma":[0.9937225,0.0005303902,0.004364132,0.00002970958,0.00001338232,0.00002200899,0.00004208182,0.00002239536,0.001253443],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006523056,"threshold_uncertainty_score":0.002182186,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006116465753143618,"score_gpt":0.2342399531650588,"score_spread":0.2281234874119152,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}