{"id":"W2911560284","doi":"10.1016/j.chempr.2019.01.005","title":"Direct Catalytic Methanol-to-Ethanol Photo-conversion via Methyl Carbene","year":2019,"lang":"en","type":"article","venue":"Chem","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":78,"is_retracted":false,"has_abstract":false,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Fonds de recherche du Québec – Nature et technologies; Canada Foundation for Innovation; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; McGill University","keywords":"Carbene; Methanol; Catalysis; Ethanol; Chemistry; Alcohol; Green chemistry; Methylene; Organic chemistry; Combinatorial chemistry; Materials science; Nanotechnology; Reaction mechanism","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0001995288,0.0003199949,0.0004253597,0.0001250699,0.00009897172,0.00006854578,0.0004441359,0.000245332,0.00333401],"category_scores_gemma":[0.0001578686,0.0003361577,0.0002354525,0.0003976259,0.00006556991,0.000142555,0.0002311449,0.000335584,0.004342107],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004237702,"about_ca_system_score_gemma":0.0001038013,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005563005,"about_ca_topic_score_gemma":0.00001370488,"domain_scores_codex":[0.9980823,0.000001242257,0.000314416,0.0007143416,0.0003820854,0.0005056574],"domain_scores_gemma":[0.9980406,0.0002404412,0.0001234182,0.001222594,0.0001143492,0.0002585582],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002855103,0.00009509402,0.0006365407,0.0002161231,0.00008971346,0.000008166528,0.0003715436,0.00003097393,0.9966658,0.000004358792,0.0007782998,0.001074853],"study_design_scores_gemma":[0.000633037,0.00001959354,0.0001230894,0.00007449954,0.0001105896,0.00002596034,0.000141114,0.0005878737,0.9813605,0.00002637851,0.01649958,0.0003978176],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.962393,0.0001684666,0.00003006076,0.0001253711,0.0005412733,0.000204748,0.00005853154,0.0003388605,0.03613968],"genre_scores_gemma":[0.9703007,0.00001242932,0.00008386026,0.0001118255,0.0001906308,0.00004169176,0.0001308759,0.0000815472,0.02904641],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01572127,"threshold_uncertainty_score":0.999909,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01015872617928693,"score_gpt":0.2504517223048821,"score_spread":0.2402929961255952,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}