{"id":"W2912466907","doi":"10.1039/c8sc05657a","title":"Synthesis of acyl(chloro)phosphines enabled by phosphinidene transfer","year":2019,"lang":"en","type":"article","venue":"Chemical Science","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":33,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; Toronto Public Health","funders":"Division of Chemistry; Natural Sciences and Engineering Research Council of Canada; Technische Universität Berlin; University of Toronto; National Science Foundation","keywords":"Phosphinidene; Chemistry; Transfer (computing); Combinatorial chemistry; Stereochemistry; Computer science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009341519,0.0003235342,0.0001056393,0.0001244982,0.000115202,0.0002141343,0.000269881,0.0003400602,0.0021389],"category_scores_gemma":[0.0001650857,0.0001137116,0.0001328804,0.0001273997,0.0001885612,0.000347494,0.0003951141,0.0004818816,0.0008481119],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001508378,"about_ca_system_score_gemma":0.0001510922,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001883021,"about_ca_topic_score_gemma":0.000319965,"domain_scores_codex":[0.9999367,0.000008017229,0.000004432718,0.00002003622,0.00001650226,0.00001434505],"domain_scores_gemma":[0.9999458,0.00001017284,0.0000208176,0.000006360488,0.000008006581,0.000008901544],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006440671,0.00002238996,0.0001065233,0.0002298511,0.000007847068,0.0002444737,0.00007507214,0.0004807653,0.9898152,0.002154911,0.0002278578,0.006570537],"study_design_scores_gemma":[0.00001711928,0.0002478759,0.000239814,0.000005737781,0.000008334969,0.0002100356,0.00001474063,0.001076823,0.9869976,0.0002188503,0.0109537,0.000009420999],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9442576,0.001992788,0.03266291,0.0002455382,0.0001206998,0.0001512338,0.0006261792,0.0004957726,0.0194473],"genre_scores_gemma":[0.9865288,0.0008289624,0.008510181,0.00005041261,0.00001287603,0.00004570935,0.0002107034,0.00004588777,0.003766608],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0021389,"threshold_uncertainty_score":0.007155359,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004427212073227269,"score_gpt":0.1980295725438819,"score_spread":0.1936023604706546,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}