{"id":"W2912466907","doi":"10.1039/c8sc05657a","title":"Synthesis of acyl(chloro)phosphines enabled by phosphinidene transfer","year":2019,"lang":"en","type":"article","venue":"Chemical Science","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":33,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; Toronto Public Health","funders":"Division of Chemistry; Natural Sciences and Engineering Research Council of Canada; Technische Universität Berlin; University of Toronto; National Science Foundation","keywords":"Phosphinidene; Chemistry; Transfer (computing); Combinatorial chemistry; Stereochemistry; Computer science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003805019,0.0002929608,0.0004903065,0.00005268696,0.0000954735,0.00006851148,0.001615024,0.0001716214,0.006457625],"category_scores_gemma":[0.0006694957,0.0002586226,0.0001535899,0.0008040277,0.0008431056,0.0003572186,0.0002131755,0.0002119541,0.0002634552],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001828196,"about_ca_system_score_gemma":0.0001760626,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001071581,"about_ca_topic_score_gemma":0.000001141668,"domain_scores_codex":[0.997146,0.000006688142,0.0004675888,0.0007948696,0.0009156816,0.000669152],"domain_scores_gemma":[0.9981062,0.0005195439,0.00009075721,0.0008637446,0.0001458586,0.0002738804],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004718107,0.0001345672,0.004536868,0.0001030067,0.00001499614,0.00000157864,0.00008512886,0.000001345973,0.9922687,0.0001194626,0.0005566764,0.002130436],"study_design_scores_gemma":[0.0002506662,0.00001024977,0.0001614054,0.00009757766,0.00002638895,0.000005955547,0.00006900317,0.0001337074,0.9967176,0.0002109777,0.001985104,0.0003313602],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9771295,0.000254323,0.00001358866,0.0002875715,0.0001205918,0.00008729872,0.00003762369,0.0001171955,0.02195227],"genre_scores_gemma":[0.9981364,0.00005329468,0.0004181641,0.00007474486,0.00004213951,0.00002222885,0.000003367546,0.00003606211,0.001213593],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02100687,"threshold_uncertainty_score":0.9999866,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004427212073227269,"score_gpt":0.1980295725438819,"score_spread":0.1936023604706546,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}