{"id":"W2912675719","doi":"10.1039/c8cs00940f","title":"Radicals derived from Lewis acid/base pairs","year":2019,"lang":"en","type":"review","venue":"Chemical Society Reviews","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":164,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; Toronto Public Health","funders":"Technische Universität Berlin; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Radical; Lewis acids and bases; Chemistry; Acceptor; Molecule; Base (topology); Combinatorial chemistry; Organic chemistry; Catalysis; Mathematics; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","research_integrity","insufficient_payload"],"category_scores_codex":[0.000359333,0.001632348,0.006339538,0.00001582095,0.0001182446,0.0001393671,0.001800326,0.002758235,0.02310027],"category_scores_gemma":[0.0005126201,0.001304546,0.006207135,0.0003596311,0.0003562464,0.0001093052,0.0006411913,0.00234277,0.004655698],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007454796,"about_ca_system_score_gemma":0.0004547055,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001141043,"about_ca_topic_score_gemma":2.678505e-7,"domain_scores_codex":[0.9941892,0.0001087594,0.00226189,0.001890895,0.0005603083,0.0009889317],"domain_scores_gemma":[0.9951389,0.0004948822,0.001234783,0.002365033,0.00005745889,0.0007089834],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.000002159913,0.0001390047,0.000003499606,0.0738323,0.0004213981,0.000007139705,0.00006167779,3.015729e-9,0.130553,0.000001792436,0.08809482,0.7068832],"study_design_scores_gemma":[0.0003441794,0.000002965191,3.115857e-8,0.0140522,0.001705124,0.0000158749,0.00001903652,0.000001628997,0.2137698,0.000009739059,0.7690004,0.001078987],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.00007980911,0.9960699,0.00001152585,0.00009613777,0.0002557169,0.0006371908,0.0005466032,0.0003286281,0.001974487],"genre_scores_gemma":[0.000005221393,0.990998,0.001268014,0.0006898188,0.0019343,0.0002901725,0.00310687,0.0002978705,0.001409679],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.7058042,"threshold_uncertainty_score":0.9999589,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.06460652271324695,"score_gpt":0.311402850169282,"score_spread":0.246796327456035,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}